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This study aims to go beyond by developing poly(isosorbide 2,5-furandicarboxylate-co-dodecanedioate) copolyesters derived from isosorbide (Is), 2,5-furandicarboxylic acid (FDCA), and 1,12-dodecanedioic acid (DDA), and studying their degradation under environmental conditions, often overlooked, namely seawater conditions. These novel polyesters have been characterized in-depth using ATR-FTIR, 1H, and 13C NMR and XRD spectroscopies and thermal analysis (TGA and DSC). They showed enhanced thermal stability (up to 330 \u00b0C), and the glass transition temperature increased with the content of FDCA from ca. 9 to 60 \u00b0C. Regarding their (bio)degradation, the enzymatic conditions lead to the highest weight loss compared to simulated seawater conditions, with values matching 27% vs. 3% weight loss after 63 days of incubation, respectively. Copolymerization of biobased FDCA, Is, and DDA represents an optimal approach for shaping the thermal\/(bio)degradation behaviors of these novel polyesters.<\/jats:p>","DOI":"10.3390\/polym14183868","type":"journal-article","created":{"date-parts":[[2022,9,16]],"date-time":"2022-09-16T01:35:10Z","timestamp":1663292110000},"page":"3868","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Isosorbide and 2,5-Furandicarboxylic Acid Based (Co)Polyesters: Synthesis, Characterization, and Environmental Degradation"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9376-383X","authenticated-orcid":false,"given":"Chaima","family":"Bouyahya","sequence":"first","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"Laboratoire des Interfaces et Mat\u00e9riaux Avanc\u00e9s, Universit\u00e9 de Monastir, Monastir 5000, Tunisia"}]},{"given":"Rafael","family":"Patr\u00edcio","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2726-5466","authenticated-orcid":false,"given":"Ana","family":"Pa\u00e7o","sequence":"additional","affiliation":[{"name":"Centre for Environmental and Marine Studies (CESAM), Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"Mafalda S.","family":"Lima","sequence":"additional","affiliation":[{"name":"Centre for Mechanical Engineering, Materials and Processes, Department of Chemical Engineering, University of Coimbra Rua S\u00edlvio Lima\u2014Polo II, 3030-790 Coimbra, Portugal"}]},{"given":"Ana C.","family":"Fonseca","sequence":"additional","affiliation":[{"name":"Centre for Mechanical Engineering, Materials and Processes, Department of Chemical Engineering, University of Coimbra Rua S\u00edlvio Lima\u2014Polo II, 3030-790 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3660-4116","authenticated-orcid":false,"given":"Teresa","family":"Rocha-Santos","sequence":"additional","affiliation":[{"name":"Centre for Environmental and Marine Studies (CESAM), Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"Mustapha","family":"Majdoub","sequence":"additional","affiliation":[{"name":"Laboratoire des Interfaces et Mat\u00e9riaux Avanc\u00e9s, Universit\u00e9 de Monastir, Monastir 5000, Tunisia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5403-8416","authenticated-orcid":false,"given":"Armando J. D.","family":"Silvestre","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3044-3016","authenticated-orcid":false,"given":"Andreia F.","family":"Sousa","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"Centre for Mechanical Engineering, Materials and Processes, Department of Chemical Engineering, University of Coimbra Rua S\u00edlvio Lima\u2014Polo II, 3030-790 Coimbra, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,9,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"387","DOI":"10.1016\/j.envpol.2018.05.008","article-title":"Current research trends on plastic pollution and ecological impacts on the soil ecosystem: A review","volume":"240","author":"Chae","year":"2018","journal-title":"Environ. 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