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Self-degassing conditions are achieved by the addition of sodium pyruvate (SP) as a ROS scavenger, while an aluminum counter electrode provides a simplified and more cost-effective electrochemical setup. Different polyacrylamides were grown on a model cellulose substrate which was previously esterified with 2-bromoisobutyrate (-BriB), serving as initiator groups. Small-scale polymerizations (15 mL) provided optimized conditions to pursue the scale-up up to 1000 mL (scale-up factor ~67). Cellulose-poly(N-isopropylacrylamide) was then chosen to prepare the tunable, thermoresponsive, solvent-free, and flexible films through a dissolution\/regeneration method. The produced films were characterized by Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), dynamic scanning calorimetry (DSC), and thermogravimetric analysis (TGA).<\/jats:p>","DOI":"10.3390\/polym14224981","type":"journal-article","created":{"date-parts":[[2022,11,18]],"date-time":"2022-11-18T04:08:40Z","timestamp":1668744520000},"page":"4981","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Scaling-Up an Aqueous Self-Degassing Electrochemically Mediated ATRP in Dispersion for the Preparation of Cellulose\u2013Polymer Composites and Films"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1858-3390","authenticated-orcid":false,"given":"Francesco","family":"De Bon","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering, Centre for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua S\u00edlvio Lima-P\u00f3lo II, 3030-790 Coimbra, Portugal"}]},{"given":"In\u00eas M.","family":"Azevedo","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Centre for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua S\u00edlvio Lima-P\u00f3lo II, 3030-790 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7342-7799","authenticated-orcid":false,"given":"Diana C. M.","family":"Ribeiro","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Centre for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua S\u00edlvio Lima-P\u00f3lo II, 3030-790 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0317-9504","authenticated-orcid":false,"given":"Rafael C.","family":"Rebelo","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Centre for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua S\u00edlvio Lima-P\u00f3lo II, 3030-790 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9351-1704","authenticated-orcid":false,"given":"Jorge F. J.","family":"Coelho","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Centre for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua S\u00edlvio Lima-P\u00f3lo II, 3030-790 Coimbra, Portugal"}]},{"given":"Arm\u00e9nio C.","family":"Serra","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Centre for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua S\u00edlvio Lima-P\u00f3lo II, 3030-790 Coimbra, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1893","DOI":"10.1007\/s10570-020-03674-w","article-title":"Cellulose and its derivatives: Towards biomedical applications","volume":"28","author":"Seddiqi","year":"2021","journal-title":"Cellulose"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"e2000619","DOI":"10.1002\/adma.202000619","article-title":"Cellulose-Based Flexible Functional Materials for Emerging Intelligent Electronics","volume":"33","author":"Zhao","year":"2021","journal-title":"Adv. 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