{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T02:36:15Z","timestamp":1773887775433,"version":"3.50.1"},"reference-count":56,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2022,12,2]],"date-time":"2022-12-02T00:00:00Z","timestamp":1669939200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"(DGRSDT) Direction g\u00e9n\u00e9rale de la Recherche Scientifique et du d\u00e9veloppement Technologique-Algeria","award":["UID\/Multi\/04044\/2019"],"award-info":[{"award-number":["UID\/Multi\/04044\/2019"]}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (FCT)","doi-asserted-by":"publisher","award":["UID\/Multi\/04044\/2019"],"award-info":[{"award-number":["UID\/Multi\/04044\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>In this work, we report a new facile method for the preparation of myrcene-limonene copolymers and nanocomposites using a Lewis acid as a catalyst (AlCl3) and organo-modified clay as a nano-reinforcing filler. The copolymer (myr-co-lim) was prepared by cationic copolymerization using AlCl3 as a catalyst. The structure of the obtained copolymer is studied and confirmed by Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, and Differential Scanning Calorimetry. By improving the dispersion of the matrix polymer in sheets of the organoclay, Maghnite-CTA+ (Mag-CTA+), an Algerian natural organophilic clay, was used to preparenanocomposites of linear copolymer (myr-co-lim). In order to identify and assess their structural, morphological, and thermal properties, the effect of the organoclay, used in varyingamounts (1, 4, 7, and 10% by weight), and the preparation process were investigated. The Mag-CTA+ is an organophylic montmorillonite silicate clay prepared through a direct exchange process in which they were used as green nano-reinforcing filler. The X-ray diffraction of the resulting nanocomposites revealed a considerable alteration in the interlayer spacing of Mag-CTA+. As a result, interlayer expansion and myr-co-lim exfoliation between layers of Mag-CTA+ were observed. Thermogravimetric analysis provided information on the synthesized nanocomposites\u2019 thermal properties. Fourier transform infrared spectroscopy and scanning electronic microscopy, respectively, were used to determine the structure and morphology of the produced nanocomposites (myr-co-lim\/Mag). The intercalation of myr-co-lim in the Mag-CTA+ sheets has been supported by the results, and the optimum amount of organoclay needed to create a nanocomposite with high thermal stability is 10% by weight. Finally, a new method for the preparation of copolymer and nanocomposites from myrcene and limonene in a short reaction time was developed.<\/jats:p>","DOI":"10.3390\/polym14235271","type":"journal-article","created":{"date-parts":[[2022,12,5]],"date-time":"2022-12-05T05:31:32Z","timestamp":1670218292000},"page":"5271","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Green Copolymers and Nanocomposites from Myrcene and Limonene Using Algerian Nano-Clay as Nano-Reinforcing Filler"],"prefix":"10.3390","volume":"14","author":[{"given":"Hodhaifa","family":"Derdar","sequence":"first","affiliation":[{"name":"Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques (CRAPC), BP 10 384, Si\u00e8ge ex-Pasna Zone Industrielle, Bou-Ismail CP 42004, Algeria"},{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7977-7610","authenticated-orcid":false,"given":"Geoffrey Robert","family":"Mitchell","sequence":"additional","affiliation":[{"name":"Centre for Rapid and Sustainable Product Development, Institute Polytechnic of Leiria, 2430-028 Marinha Grande, Portugal"}]},{"given":"Artur","family":"Mateus","sequence":"additional","affiliation":[{"name":"Centre for Rapid and Sustainable Product Development, Institute Polytechnic of Leiria, 2430-028 Marinha Grande, Portugal"}]},{"given":"Sarra","family":"Chaibedraa","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"}]},{"given":"Zinelabidine Otmane","family":"Elabed","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0041-0275","authenticated-orcid":false,"given":"Vidhura Subash","family":"Mahendra","sequence":"additional","affiliation":[{"name":"School of Chemistry Food Science and Pharmacy, University of Reading, P.O. Box 217, Reading RG6 6AD, UK"}]},{"given":"Zakaria","family":"Cherifi","sequence":"additional","affiliation":[{"name":"Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques (CRAPC), BP 10 384, Si\u00e8ge ex-Pasna Zone Industrielle, Bou-Ismail CP 42004, Algeria"},{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0624-8480","authenticated-orcid":false,"given":"Khaldoun","family":"Bachari","sequence":"additional","affiliation":[{"name":"Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques (CRAPC), BP 10 384, Si\u00e8ge ex-Pasna Zone Industrielle, Bou-Ismail CP 42004, Algeria"}]},{"given":"Redouane","family":"Chebout","sequence":"additional","affiliation":[{"name":"Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques (CRAPC), BP 10 384, Si\u00e8ge ex-Pasna Zone Industrielle, Bou-Ismail CP 42004, Algeria"}]},{"given":"Rachid","family":"Meghabar","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"}]},{"given":"Amine","family":"Harrane","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"},{"name":"Department of Chemistry, FSEI University of Abdelhamid Ibn Badis, Mostaganem 27000, Algeria"}]},{"given":"Mohammed","family":"Belbachir","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Polym\u00e8res (LCP), D\u00e9partement de Chimie, FSEA, Oran1 University, Ahmed Benbella BP N\u00b0 1524 El M\u2019Naouar, Oran 31000, Algeria"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"107","DOI":"10.1680\/gmat.14.00005","article-title":"Synthetic strategies, sustainability and biological applications of malic acid\u2013based polymers","volume":"3","author":"King","year":"2014","journal-title":"Green Mater."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1680\/jgrma.15.00004","article-title":"Synthesis of cardanol oil building blocks for polymer synthesis","volume":"3","author":"Jaillet","year":"2015","journal-title":"Green Mater."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1680\/gmat.12.00013","article-title":"Synthesis and characterization of a novel rosin-based monomer: Free-radical polymerization and epoxy curing","volume":"2","author":"Wang","year":"2013","journal-title":"Green Mater."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1127","DOI":"10.4155\/fmc.14.71","article-title":"Synthesis of medicinally relevant terpenes: Reducing the cost and time of drug discovery","volume":"6","author":"Jansen","year":"2014","journal-title":"Future Med. 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