{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,4]],"date-time":"2026-05-04T11:48:52Z","timestamp":1777895332977,"version":"3.51.4"},"reference-count":136,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2026,2,15]],"date-time":"2026-02-15T00:00:00Z","timestamp":1771113600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["Reference- PD21-00024"],"award-info":[{"award-number":["Reference- PD21-00024"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>The rapid accumulation of plastic waste and the depletion of fossil resources have intensified global efforts to develop biodegradable polymeric materials derived from renewable feedstocks. In this context, starch-based films have emerged as one of the most promising alternatives to conventional petroleum-based plastics, owing to their wide availability, low cost, biodegradability, and ability to form continuous films using simple and scalable processing techniques. Starch is a naturally occurring polysaccharide composed primarily of amylose and amylopectin, whose molecular structure is rich in hydroxyl (\u2013OH) groups. These functional groups promote extensive intermolecular hydrogen bonding, enabling starch gelatinization and film formation in aqueous systems. However, the same hydroxyl-rich structure confers a pronounced hydrophilic character, resulting in high moisture sensitivity, poor water vapor barrier properties, and limited dimensional stability under humid. Consequently, improving the hydrophobicity of starch-based films remains one of the most critical challenges for their practical application in food packaging. This review aims to summarize and critically discuss the main strategies reported for improving the hydrophobicity of starch-based films. The review focuses on composition and processing approaches, including (i) chemical modification of starch, (ii) incorporation of hydrophobic additives, (iii) reinforcement with natural fibers and nanocellulosic materials, (iv) polymer blending and multilayer\/gradient architectures, and (v) processing strategies, including film homogenization, shear treatment and aging conditions. Emphasis is placed on the mechanisms governing hydrophobicity enhancement, comparative performance indicators, and current limitations.<\/jats:p>","DOI":"10.3390\/polym18040490","type":"journal-article","created":{"date-parts":[[2026,2,16]],"date-time":"2026-02-16T14:09:54Z","timestamp":1771250994000},"page":"490","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Hydrophobicity Strategies of Starch-Based Films: Recent Advances and Perspectives"],"prefix":"10.3390","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0301-6182","authenticated-orcid":false,"given":"Elsa F.","family":"Vieira","sequence":"first","affiliation":[{"name":"REQUIMTE\/LAQV, Instituto Superior de Engenharia do Porto, Instituto Polit\u00e9cnico do Porto Rua Dr. Ant\u00f3nio Bernardino de Almeida 431, 4249-015 Porto, Portugal"}]},{"given":"Tom\u00e1s","family":"Amaral","sequence":"additional","affiliation":[{"name":"REQUIMTE\/LAQV, Instituto Superior de Engenharia do Porto, Instituto Polit\u00e9cnico do Porto Rua Dr. Ant\u00f3nio Bernardino de Almeida 431, 4249-015 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3472-849X","authenticated-orcid":false,"given":"Valentina F.","family":"Domingues","sequence":"additional","affiliation":[{"name":"REQUIMTE\/LAQV, Instituto Superior de Engenharia do Porto, Instituto Polit\u00e9cnico do Porto Rua Dr. Ant\u00f3nio Bernardino de Almeida 431, 4249-015 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3924-776X","authenticated-orcid":false,"given":"Cristina","family":"Delerue-Matos","sequence":"additional","affiliation":[{"name":"REQUIMTE\/LAQV, Instituto Superior de Engenharia do Porto, Instituto Polit\u00e9cnico do Porto Rua Dr. Ant\u00f3nio Bernardino de Almeida 431, 4249-015 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2026,2,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Soni, R., Debbarma, P., Suyal, D.C., and Goel, R. (2024). Global scenario of plastic production, consumption, and waste generation and their impacts on environment and human health. Advanced Strategies for Biodegradation of Plastic Polymers, Springer.","DOI":"10.1007\/978-3-031-55661-6"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"3724","DOI":"10.1039\/D5SU00225G","article-title":"Circular plastic economy for sustainable development: Current advances and future perspectives","volume":"3","author":"Anwar","year":"2025","journal-title":"RSC Sustain."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"21447","DOI":"10.1039\/D1RA00353D","article-title":"Ocean plastics: Environmental implications and potential routes for mitigation\u2014A perspective","volume":"11","author":"Watt","year":"2021","journal-title":"RSC Adv."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1168","DOI":"10.1126\/science.adr3837","article-title":"Pathways to reduce global plastic waste mismanagement and greenhouse gas emissions by 2050","volume":"386","author":"Pottinger","year":"2024","journal-title":"Science"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"147149","DOI":"10.1016\/j.scitotenv.2021.147149","article-title":"Microplastics in polar regions: An early warning to the world\u2019s pristine ecosystem","volume":"784","author":"Mishra","year":"2021","journal-title":"Sci. Total Environ."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"478","DOI":"10.1007\/s11270-025-08092-x","article-title":"Plastic waste in marine ecosystems: Identification techniques and policy interventions","volume":"236","author":"Das","year":"2025","journal-title":"Water Air Soil Pollut."},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Visco, A., Scolaro, C., Facchin, M., Brahimi, S., Belhamdi, H., Gatto, V., and Beghetto, V. (2022). Agri-food wastes for bioplastics: European prospective on possible applications in their second life for a circular economy. Polymers, 14.","DOI":"10.3390\/polym14132752"},{"key":"ref_8","doi-asserted-by":"crossref","unstructured":"Kuddus, M. (2021). General structure and classification of bioplastics and biodegradable plastics. Bioplastics for Sustainable Development, Springer.","DOI":"10.1007\/978-981-16-1823-9"},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Arruda, T.R., Machado, G.D.O., Marques, C.S., Souza, A.L.D., Pelissari, F.M., Oliveira, T.V.D., and Silva, R.R.A. (2025). An overview of starch-based materials for sustainable food packaging: Recent advances, limitations, and perspectives. Macromol, 5.","DOI":"10.3390\/macromol5020019"},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Vicente, D., Proen\u00e7a, D.N., and Morais, P.V. (2023). The role of bacterial polyhydroalkanoate (PHA) in a sustainable future: A review on the biological diversity. Int. J. Environ. Res. Public Health, 20.","DOI":"10.3390\/ijerph20042959"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1039\/D3FB00211J","article-title":"Starch-based edible packaging: Rheological, thermal, mechanical, microstructural, and barrier properties\u2014A review","volume":"2","author":"Santhosh","year":"2024","journal-title":"Sustain. Food Technol."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.tifs.2014.12.008","article-title":"Impact of ultrasound on structure, physicochemical properties, modifications, and applications of starch","volume":"43","author":"Zhu","year":"2015","journal-title":"Trends Food Sci. Technol."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"114005","DOI":"10.1016\/j.lwt.2022.114005","article-title":"Improving the hydrophobicity and mechanical properties of starch nanofibrous films by electrospinning and cross-linking for food packaging applications","volume":"169","author":"Zhu","year":"2022","journal-title":"LWT"},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Koch, K. (2018). Starch-based films. Starch in Food, Woodhead Publishing.","DOI":"10.1016\/B978-0-08-100868-3.00019-6"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"110788","DOI":"10.1016\/j.eurpolymj.2021.110788","article-title":"Major factors affecting the characteristics of starch based biopolymer films","volume":"160","author":"Agarwal","year":"2021","journal-title":"Eur. Polym. J."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Dorantes-Fuertes, M.G., L\u00f3pez-M\u00e9ndez, M.C., Mart\u00ednez-Castellanos, G., Mel\u00e9ndez-Armenta, R.\u00c1., and Jim\u00e9nez-Mart\u00ednez, H.E. (2024). Starch extraction methods in tubers and roots: A systematic review. Agronomy, 14.","DOI":"10.3390\/agronomy14040865"},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Ribba, L., Garcia, N.L., D\u2019Accorso, N., and Goyanes, S. (2017). Disadvantages of starch-based materials, feasible alternatives in order to overcome these limitations. Starch-Based Materials in Food Packaging: Processing, Characterization and Applications, Elsevier.","DOI":"10.1016\/B978-0-12-809439-6.00003-0"},{"key":"ref_18","doi-asserted-by":"crossref","unstructured":"Mu\u00f1oz-Gimena, P.F., Oliver-Cuenca, V., Peponi, L., and L\u00f3pez, D. (2023). A review on reinforcements and additives in starch-based composites for food packaging. Polymers, 15.","DOI":"10.3390\/polym15132972"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"143793","DOI":"10.1016\/j.foodchem.2025.143793","article-title":"Improving the hydrophobic nature of biopolymer based edible packaging film: A review","volume":"479","author":"Kalita","year":"2025","journal-title":"Food Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"101431","DOI":"10.1016\/j.fpsl.2025.101431","article-title":"Lignocellulosic fiber-reinforced starch thermoplastic composites for food packaging application: A review","volume":"47","author":"Nazrin","year":"2025","journal-title":"Food Packag. Shelf Life"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"e27453","DOI":"10.1016\/j.heliyon.2024.e27453","article-title":"Recent advances in modified starch based biodegradable food packaging: A review","volume":"10","author":"Fatima","year":"2024","journal-title":"Heliyon"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"e70071","DOI":"10.1002\/star.70071","article-title":"Crosslinking modification for starch and starch-based films (a review)","volume":"77","author":"Kalu","year":"2025","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1645","DOI":"10.1002\/fft2.70040","article-title":"A comprehensive review of starch: Structure, properties, chemical modification, and application in food preservation","volume":"6","author":"Xie","year":"2025","journal-title":"Food Front."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"103920","DOI":"10.1016\/j.fbio.2024.103920","article-title":"Regulation of fine structure of different types of natural waxes by octenyl succinate starch in starch bioplastics","volume":"59","author":"Gao","year":"2024","journal-title":"Food Biosci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1013","DOI":"10.1016\/j.ijbiomac.2021.10.081","article-title":"Mechanical and barrier properties of starch blend films enhanced with kaolin for application in food packaging","volume":"192","author":"Rammak","year":"2021","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1987","DOI":"10.3390\/polym14101987","article-title":"Effect on the properties of edible starch-based films by the incorporation of additives: A review","volume":"14","author":"Singh","year":"2022","journal-title":"Polymers"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1464","DOI":"10.1515\/ntrev-2022-0094","article-title":"Mechanical, thermal, and barrier properties of starch films incorporated with chitosan nanoparticles","volume":"11","author":"Othman","year":"2022","journal-title":"Nanotechnol. Rev."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"100095","DOI":"10.1016\/j.clcb.2024.100095","article-title":"Optimizing film mechanical and water contact angle properties via PLA\/starch\/lecithin concentrations","volume":"8","author":"Mukaila","year":"2024","journal-title":"Clean. Circ. Bioeconomy"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"118582","DOI":"10.1016\/j.indcrop.2024.118582","article-title":"Effect of hydrophobic nano-silica content on the surface properties of corn-starch films","volume":"214","author":"Jeznach","year":"2024","journal-title":"Ind. Crops Prod."},{"key":"ref_30","doi-asserted-by":"crossref","unstructured":"Cai, J., Hafeez, M.A., Wang, Q., Farooq, S., Huang, Q., and Xiao, J. (2022). Biopolymer-based functional films for packaging applications: A review. Front. Nutr., 9.","DOI":"10.3389\/fnut.2022.1000116"},{"key":"ref_31","doi-asserted-by":"crossref","unstructured":"Jayarathna, S., Andersson, M., and Andersson, R. (2022). Recent advances in starch-based blends and composites for bioplastics applications. Polymers, 14.","DOI":"10.3390\/polym14214557"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"360","DOI":"10.1007\/s12393-023-09342-6","article-title":"Hydrophobic biopolymer-based films: Strategies, properties, and food applications","volume":"15","author":"Cui","year":"2023","journal-title":"Food Eng. Rev."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"123679","DOI":"10.1016\/j.polymer.2021.123679","article-title":"Facile fabrication of thermoplastic starch\/poly (lactic acid) multilayer films with superior gas and moisture barrier properties","volume":"223","author":"Trinh","year":"2021","journal-title":"Polymer"},{"key":"ref_34","doi-asserted-by":"crossref","unstructured":"Bayer, I.S. (2021). Biopolymers in multilayer films for long-lasting protective food packaging: A review. Sustainable Food Packaging Technology, Wiley.","DOI":"10.1002\/9783527820078.ch15"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"4642","DOI":"10.1021\/acsapm.4c00224","article-title":"Enhanced functional properties for packaging applications using sodium alginate\/starch bilayer and multilayer films","volume":"6","author":"Kiattijiranon","year":"2024","journal-title":"ACS Appl. Polym. Mater."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"133609","DOI":"10.1016\/j.foodchem.2022.133609","article-title":"Reinforcement of starch film with Castanea sativa shells polysaccharides: Optimized formulation and characterization","volume":"396","author":"Amaral","year":"2022","journal-title":"Food Chem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"119375","DOI":"10.1016\/j.indcrop.2024.119375","article-title":"Starch-based films: Tuning physical properties driven by nanocellulose\u2013natural rubber latex composites","volume":"221","author":"Freitas","year":"2024","journal-title":"Ind. Crops Prod."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"130399","DOI":"10.1016\/j.ijbiomac.2024.130399","article-title":"Recent advances in reinforced bioplastics for food packaging\u2014A critical review","volume":"263","author":"Siddiqui","year":"2024","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"7838","DOI":"10.1002\/pc.29520","article-title":"Valorization of chestnut processing wastes into bio-based composites and bioplastics: A review","volume":"46","author":"Silva","year":"2025","journal-title":"Polym. Compos."},{"key":"ref_40","doi-asserted-by":"crossref","unstructured":"Tan, S.X., Andriyana, A., Ong, H.C., Lim, S., Pang, Y.L., and Ngoh, G.C. (2022). Roles of nanofillers and plasticizers towards sustainable starch-based bioplastic fabrication. Polymers, 14.","DOI":"10.3390\/polym14040664"},{"key":"ref_41","doi-asserted-by":"crossref","unstructured":"Visakh, P.M. (2025). Starch-based nanocomposite for food packaging applications. Engineering Applications of Polymer-Based Nanocomposites, Springer.","DOI":"10.1007\/978-3-031-93463-6"},{"key":"ref_42","doi-asserted-by":"crossref","unstructured":"Basavegowda, N., and Baek, K.H. (2021). Advances in functional biopolymer-based nanocomposites for active food packaging applications. Polymers, 13.","DOI":"10.3390\/polym13234198"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"106069","DOI":"10.1016\/j.ultsonch.2022.106069","article-title":"Physical, mechanical, thermal and barrier properties of starch nanoparticle\/polyurethane nanocomposite films synthesized by an ultrasound-assisted process","volume":"88","author":"Hakke","year":"2022","journal-title":"Ultrason. Sonochem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"115566","DOI":"10.1016\/j.indcrop.2022.115566","article-title":"DES-ultrasonication processing for cellulose nanofiber and its compounding in biodegradable starch-based packaging films through extrusion","volume":"188","author":"Kesari","year":"2022","journal-title":"Ind. Crops Prod."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"109376","DOI":"10.1016\/j.foodhyd.2023.109376","article-title":"Effects of ultrasonic and ozone modification on the morphology, mechanical, thermal and barrier properties of corn starch films","volume":"147","author":"Huang","year":"2024","journal-title":"Food Hydrocoll."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"127973","DOI":"10.1016\/j.ijbiomac.2023.127973","article-title":"Starch films loaded with tannin: Study of rheological and physical properties","volume":"254","author":"Mileti","year":"2024","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"1079","DOI":"10.1016\/j.ijbiomac.2019.03.190","article-title":"Starch-based films: Major factors affecting their properties","volume":"132","author":"Thakur","year":"2019","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_48","doi-asserted-by":"crossref","unstructured":"Bertoft, E. (2017). Understanding starch structure: Recent progress. Agronomy, 7.","DOI":"10.3390\/agronomy7030056"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"117039","DOI":"10.1016\/j.carbpol.2020.117039","article-title":"Formation of high amylose corn starch\/konjac glucomannan composite film with improved mechanical and barrier properties","volume":"251","author":"Zou","year":"2021","journal-title":"Carbohydr. Polym."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"8568","DOI":"10.1080\/10408398.2022.2056871","article-title":"High-amylose starch: Structure, functionality and applications","volume":"63","author":"Zhong","year":"2023","journal-title":"Crit. Rev. Food Sci. Nutr."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"238","DOI":"10.1016\/j.foodhyd.2019.03.026","article-title":"Structure and functional properties of waxy starches","volume":"94","author":"Hsieh","year":"2019","journal-title":"Food Hydrocoll."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"4198","DOI":"10.1080\/87559129.2021.2021936","article-title":"An insight into the physicochemical characterisation of starch-lipid complex and its importance in food industry","volume":"39","author":"Sengupta","year":"2023","journal-title":"Food Rev. Int."},{"key":"ref_53","doi-asserted-by":"crossref","unstructured":"Domene-L\u00f3pez, D., Garc\u00eda-Quesada, J.C., Martin-Gullon, I., and Montalb\u00e1n, M.G. (2019). Influence of starch composition and molecular weight on physicochemical properties of biodegradable films. Polymers, 11.","DOI":"10.3390\/polym11071084"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"2731","DOI":"10.1080\/10408398.2024.2349735","article-title":"The application of starch-based edible film in food preservation: A comprehensive review","volume":"65","author":"Wang","year":"2025","journal-title":"Crit. Rev. Food Sci. Nutr."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"116500","DOI":"10.1016\/j.foodres.2025.116500","article-title":"Innovative non-thermal processing: Unraveling structural and functional transformations in food macromolecules\u2014Starch, proteins, and lipids","volume":"212","author":"Jia","year":"2025","journal-title":"Food Res. Int."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"140922","DOI":"10.1016\/j.ijbiomac.2025.140922","article-title":"Effects of deacetylated konjac glucomannan on retrogradation properties of pea, mung bean and potato starches during storage","volume":"304","author":"Yu","year":"2025","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"1328","DOI":"10.1016\/j.foodhyd.2008.09.002","article-title":"Effect of cellulose fibers addition on the mechanical properties and water vapor barrier of starch-based films","volume":"23","author":"Laurindo","year":"2009","journal-title":"Food Hydrocoll."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1016\/j.ijbiomac.2021.07.050","article-title":"A comprehensive review of the factors influencing the formation of retrograded starch","volume":"186","author":"Chang","year":"2021","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_59","doi-asserted-by":"crossref","unstructured":"\u017bo\u0142ek-Tryznowska, Z., and Ka\u0142u\u017ca, A. (2021). The influence of starch origin on the properties of starch films: Packaging performance. Materials, 14.","DOI":"10.3390\/ma14051146"},{"key":"ref_60","doi-asserted-by":"crossref","unstructured":"Bangar, S.P., Purewal, S.S., Trif, M., Maqsood, S., Kumar, M., Manjunatha, V., and Rusu, A.V. (2021). Functionality and applicability of starch-based films: An eco-friendly approach. Foods, 10.","DOI":"10.3390\/foods10092181"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/j.ijbiomac.2021.08.027","article-title":"Thermoplastic starch blown films with improved mechanical and barrier properties","volume":"188","author":"Dang","year":"2021","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_62","doi-asserted-by":"crossref","unstructured":"Qiu, C., Hu, H., Chen, B., Lin, Q., Ji, H., and Jin, Z. (2024). Research progress on the physicochemical properties of starch-based foods by extrusion processing. Foods, 13.","DOI":"10.3390\/foods13223677"},{"key":"ref_63","doi-asserted-by":"crossref","unstructured":"Roy, S., and Shahid, M. (2026). Starch-Based polymers in food packaging: Recent advances. Biomaterials for Sustainable Food Packaging. Environmental Footprints and Eco-Design of Products and Processes, Springer.","DOI":"10.1007\/978-3-032-08027-1"},{"key":"ref_64","doi-asserted-by":"crossref","unstructured":"Shakil, F. (2024). Reactive extrusion: Filled polymer compounds and its applications. Polymer Composites: From Computational to Experimental Aspects, Springer.","DOI":"10.1007\/978-981-97-0888-8_12"},{"key":"ref_65","doi-asserted-by":"crossref","unstructured":"Gonz\u00e1lez-Torres, B., Robles-Garc\u00eda, M.\u00c1., Guti\u00e9rrez-Lomel\u00ed, M., Padilla-Frausto, J.J., Navarro-Villarruel, C.L., Del-Toro-S\u00e1nchez, C.L., and Reynoso-Mar\u00edn, F.J. (2021). Combination of sorbitol and glycerol, as plasticizers, and oxidized starch improves physicochemical characteristics of films for food preservation. Polymers, 13.","DOI":"10.3390\/polym13193356"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"581","DOI":"10.1016\/j.ijbiomac.2020.03.218","article-title":"The effect of plasticizers on thermoplastic starch films developed from Anchote starch","volume":"155","author":"Abera","year":"2020","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_67","first-page":"201600161","article-title":"Characteristics of starch-based films produced using glycerol and 1-butyl-3-methylimidazolium chloride as combined plasticizers","volume":"69","author":"Ren","year":"2016","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"115545","DOI":"10.1016\/j.carbpol.2019.115545","article-title":"Electroconductive starch\/multiwalled carbon nanotube films plasticized by 1-ethyl-3-methylimidazolium acetate","volume":"229","year":"2020","journal-title":"Carbohydr. Polym."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"342","DOI":"10.1016\/j.indcrop.2016.04.015","article-title":"Optimization of physical and optical properties of biodegradable edible films based on pea starch and guar gum","volume":"86","author":"Saberi","year":"2016","journal-title":"Ind. Crops Prod."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"1162","DOI":"10.1016\/j.carbpol.2016.10.079","article-title":"Gelatin\/potato starch edible biocomposite films: Correlation between morphology and physical properties","volume":"157","author":"Podshivalov","year":"2017","journal-title":"Carbohydr. Polym."},{"key":"ref_71","first-page":"1","article-title":"Antifungal starch-based edible films containing Aloe vera","volume":"72","author":"Santamarina","year":"2017","journal-title":"Food Hydrocoll."},{"key":"ref_72","doi-asserted-by":"crossref","unstructured":"Thakur, V.K., Thakur, M.K., and Kessler, M.R. (2017). Strategies to improve the functionality of starch-based films. Handbook of Composites from Renewable Materials, Vol. 4: Functionalization, Wiley.","DOI":"10.1002\/9781119441632"},{"key":"ref_73","doi-asserted-by":"crossref","unstructured":"Chauhan, O.P. (2022). Starch gelatinization and modification. Advances in Food Chemistry, Springer.","DOI":"10.1007\/978-981-19-4796-4"},{"key":"ref_74","unstructured":"(2002). Standard Test Method for Tensile Properties of Thin Plastic Sheeting. Annual Book of Astm Standards (Standard No. ASTM D882). Available online: https:\/\/www.instron.us\/en-us\/testing-solutions\/by-test-type\/tension\/astm-d882."},{"key":"ref_75","doi-asserted-by":"crossref","unstructured":"Guti\u00e9rrez, T.J., Ollier, R., and Alvarez, V.A. (2017). Surface properties of thermoplastic starch materials reinforced with natural fillers. Functional Biopolymers, Springer International Publishing.","DOI":"10.1007\/978-3-319-66417-0_5"},{"key":"ref_76","doi-asserted-by":"crossref","unstructured":"Zhang, M., Jia, H., Wang, B., Ma, C., He, F., Fan, Q., and Liu, W. (2023). A prospective review on the research progress of citric acid modified starch. Foods, 12.","DOI":"10.3390\/foods12030458"},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"1095","DOI":"10.1038\/s41428-025-01051-7","article-title":"Development of functional degradable materials by precise crosslinking design of biobased polymers","volume":"57","author":"Hsu","year":"2025","journal-title":"Polym. J."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"141526","DOI":"10.1016\/j.ijbiomac.2025.141526","article-title":"A comprehensive review on methods, mechanisms, properties, and emerging applications of crosslinked starches","volume":"306","author":"Kumar","year":"2025","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1007\/s10965-019-1983-2","article-title":"Esterification of starch in search of a biodegradable thermoplastic material","volume":"27","author":"Anannya","year":"2020","journal-title":"J. Polym. Res."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"1900238","DOI":"10.1002\/star.201900238","article-title":"Recent advances in the preparation and characterization of intermediately to highly esterified and etherified starches: A review","volume":"72","author":"Xu","year":"2020","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"3334","DOI":"10.1080\/10408398.2024.2365343","article-title":"Properties and functions of acylated starch with short-chain fatty acids: A comprehensive review","volume":"65","author":"Li","year":"2025","journal-title":"Crit. Rev. Food Sci. Nutr."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"2200117","DOI":"10.1002\/star.202200117","article-title":"Impact of various modification methods on physicochemical and functional properties of starch: A review","volume":"75","author":"Sinhmar","year":"2023","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"1148","DOI":"10.1111\/1541-4337.13107","article-title":"Biopolymers as green-based food packaging materials: A focus on modified and unmodified starch-based films","volume":"22","author":"Matheus","year":"2023","journal-title":"Compr. Rev. Food Sci. Food Saf."},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"2200025","DOI":"10.1002\/star.202200025","article-title":"Recent developments in starch modification by organic acids: Aeview","volume":"74","author":"Karma","year":"2022","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"e70101","DOI":"10.1111\/1541-4337.70101","article-title":"Sorghum starch: Composition, structure, functionality, and strategies for its improvement","volume":"24","author":"Zahid","year":"2025","journal-title":"Compr. Rev. Food Sci. Food Saf."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1016\/j.tifs.2015.07.011","article-title":"Food applications of emulsion-based edible films and coatings","volume":"45","author":"Galus","year":"2015","journal-title":"Trends Food Sci. Technol."},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"104643","DOI":"10.1016\/j.tifs.2024.104643","article-title":"Applications in Pickering emulsions of enhancing preservation properties: Current trends and future prospects in active food packaging coatings and films","volume":"151","author":"Cheng","year":"2024","journal-title":"Trends Food Sci. Technol."},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1016\/j.tifs.2019.01.012","article-title":"Starch based Pickering emulsions: Fabrication, properties, and applications","volume":"85","author":"Zhu","year":"2019","journal-title":"Trends Food Sci. Technol."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"105149","DOI":"10.1016\/j.tifs.2025.105149","article-title":"Essential oil-embedded starch based films for active packaging: Insights into migration, stability, and preservation efficiency","volume":"163","author":"Gupta","year":"2025","journal-title":"Trends Food Sci. Technol."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"515","DOI":"10.1016\/j.ijbiomac.2022.01.181","article-title":"Recent advancement in improvement of properties of polysaccharides and proteins based packaging film with added nanoparticles: A review","volume":"203","author":"Akhila","year":"2022","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_91","doi-asserted-by":"crossref","unstructured":"Rivadeneira-Velasco, K.E., Utreras-Silva, C.A., D\u00edaz-Barrios, A., Sommer-M\u00e1rquez, A.E., Tafur, J.P., and Michell, R.M. (2021). Green nanocomposites based on thermoplastic starch: A review. Polymers, 13.","DOI":"10.3390\/polym13193227"},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"2260","DOI":"10.1080\/10408398.2021.1973955","article-title":"Bio-based multilayer films: A review of the principal methods of production and challenges","volume":"63","author":"Kubo","year":"2023","journal-title":"Crit. Rev. Food Sci. Nutr."},{"key":"ref_93","doi-asserted-by":"crossref","unstructured":"Periyasamy, T., Asrafali, S.P., and Lee, J. (2025). Recent advances in functional biopolymer films with antimicrobial and antioxidant properties for enhanced food packaging. Polymers, 17.","DOI":"10.3390\/polym17091257"},{"key":"ref_94","doi-asserted-by":"crossref","unstructured":"Sun, Q. (2018). Starch nanoparticles. Starch in Food, Elsevier.","DOI":"10.1016\/B978-0-08-100868-3.00018-4"},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1016\/j.foodchem.2019.01.015","article-title":"Simple ultrasound method to obtain starch micro- and nanoparticles from cassava, corn and yam starches","volume":"283","author":"Minakawa","year":"2019","journal-title":"Food Chem."},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"1287","DOI":"10.1016\/j.apt.2016.04.021","article-title":"Fast and scalable preparation of starch nanoparticles by stirred media milling","volume":"27","author":"Patel","year":"2016","journal-title":"Adv. Powder Technol."},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"105677","DOI":"10.1016\/j.foodhyd.2020.105677","article-title":"Modification of resistant starch nanoparticles using high-pressure homogenization treatment","volume":"103","author":"Apostolidis","year":"2020","journal-title":"Food Hydrocoll."},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"6357","DOI":"10.1021\/acs.jafc.8b01370","article-title":"Starch spherulites prepared by a combination of enzymatic and acid hydrolysis of normal corn starch","volume":"66","author":"Shang","year":"2018","journal-title":"J. Agric. Food Chem."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.carbpol.2017.10.015","article-title":"Preparation and characterization of starch nanocrystals combining ball milling with acid hydrolysis","volume":"180","author":"Dai","year":"2018","journal-title":"Carbohydr. Polym."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"012021","DOI":"10.1088\/1742-6596\/1481\/1\/012021","article-title":"Preparation and characterization of sago (Metroxylon sp.) starch nanoparticles using hydrolysis-precipitation method","volume":"1481","author":"Maryam","year":"2020","journal-title":"J. Phys. Conf. Ser."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"372","DOI":"10.35741\/issn.0258-2724.56.3.31","article-title":"Breadfruit-based starch nanoparticles prepared using nanoprecipitation to stabilize a Pickering emulsion","volume":"56","author":"Harsanto","year":"2021","journal-title":"J. Southwest Jiaotong Univ."},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"114481","DOI":"10.1016\/j.indcrop.2021.114481","article-title":"Starch films containing starch nanoparticles as produced in a single step green route","volume":"177","author":"Bernardo","year":"2022","journal-title":"Ind. Crops Prod."},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"1800028","DOI":"10.1002\/star.201800028","article-title":"Nanocomposite films from mango kernel or corn starch with starch nanocrystals","volume":"70","author":"Oliveira","year":"2018","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_104","doi-asserted-by":"crossref","unstructured":"Garavand, Y., Taheri-Garavand, A., Garavand, F., Shahbazi, F., Khodaei, D., and Cacciotti, I. (2022). Starch-polyvinyl alcohol-based films reinforced with chitosan nanoparticles: Physical, mechanical, structural, thermal and antimicrobial properties. Appl. Sci., 12.","DOI":"10.3390\/app12031111"},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"2413","DOI":"10.1007\/s10570-024-05753-8","article-title":"Carboxymethyl cellulose\/starch-based films incorporating chitosan nanoparticles for multifunctional food packaging","volume":"31","author":"Amaregouda","year":"2024","journal-title":"Cellulose"},{"key":"ref_106","doi-asserted-by":"crossref","first-page":"101032","DOI":"10.1016\/j.fpsl.2023.101032","article-title":"Incorporation of oxidized debranched starch\/chitosan nanoparticles for enhanced hydrophobicity of corn starch films","volume":"35","author":"Liu","year":"2023","journal-title":"Food Packag. Shelf Life"},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/j.compositesa.2016.10.003","article-title":"The roles of nanoparticles accumulation and interphase properties in properties of polymer particulate nanocomposites by a multi-step methodology","volume":"91","author":"Zare","year":"2016","journal-title":"Compos. Part A Appl. Sci. Manuf."},{"key":"ref_108","doi-asserted-by":"crossref","first-page":"2589","DOI":"10.1007\/s10924-021-02363-4","article-title":"Composites bioplastic film for various concentration of zinc oxide (ZnO) nanocrystals towards physical properties for high biodegradability in soil and seawater","volume":"30","author":"Anugrahwidya","year":"2022","journal-title":"J. Polym. Environ."},{"key":"ref_109","doi-asserted-by":"crossref","first-page":"3893","DOI":"10.1002\/fsn3.2371","article-title":"The synergistic effects of zinc oxide nanoparticles and fennel essential oil on physicochemical, mechanical, and antibacterial properties of potato starch films","volume":"9","author":"Babapour","year":"2021","journal-title":"Food Sci. Nutr."},{"key":"ref_110","doi-asserted-by":"crossref","first-page":"743","DOI":"10.1016\/j.ijbiomac.2019.11.244","article-title":"The synergistic effects of cinnamon essential oil and nano TiO2 on antimicrobial and functional properties of sago starch films","volume":"157","author":"Arezoo","year":"2020","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_111","doi-asserted-by":"crossref","first-page":"106719","DOI":"10.1016\/j.foodhyd.2021.106719","article-title":"Composite film based on potato starch\/apple peel pectin\/ZrO2 nanoparticles\/microencapsulated Zataria multiflora essential oil: Investigation of physicochemical properties and use in quail meat packaging","volume":"117","author":"Sani","year":"2021","journal-title":"Food Hydrocoll."},{"key":"ref_112","doi-asserted-by":"crossref","unstructured":"Sun, J., Wang, S., Duan, J.A., and Xiao, P. (2025). Eco-friendly processing and application of food-derived polysaccharides: Advances in extraction, separation and drying. Food Rev. Int., 1\u201335.","DOI":"10.1080\/87559129.2025.2553683"},{"key":"ref_113","doi-asserted-by":"crossref","first-page":"100803","DOI":"10.1016\/j.fpsl.2021.100803","article-title":"Nanoclay-based active food packaging systems: A review","volume":"31","author":"Nath","year":"2022","journal-title":"Food Packag. Shelf Life"},{"key":"ref_114","doi-asserted-by":"crossref","unstructured":"Ren, J., Dang, K., Pollet, E., and Av\u00e9rous, L. (2018). Preparation and characterization of thermoplastic potato starch\/halloysite nano-biocomposites: Effect of plasticizer nature and nanoclay content. Polymers, 10.","DOI":"10.3390\/polym10080808"},{"key":"ref_115","doi-asserted-by":"crossref","unstructured":"Sun, J., Yang, X., Bai, Y., Fang, Z., Zhang, S., Wang, X., and Guo, Y. (2024). Recent advances in cellulose nanofiber modification and characterization and cellulose nanofiber-based films for eco-friendly active food packaging. Foods, 13.","DOI":"10.3390\/foods13243999"},{"key":"ref_116","doi-asserted-by":"crossref","first-page":"935","DOI":"10.1007\/s10570-015-0551-0","article-title":"Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: A review","volume":"22","author":"Jonoobi","year":"2015","journal-title":"Cellulose"},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"1048","DOI":"10.1016\/j.ijbiomac.2020.05.046","article-title":"Cellulose nanocrystals from grape pomace and their use for the development of starch-based nanocomposite films","volume":"159","author":"Silva","year":"2020","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"1700139","DOI":"10.1002\/star.201700139","article-title":"UV resistant transparent bionanocomposite films based on potato starch\/cellulose for sustainable packaging","volume":"70","author":"Balakrishnan","year":"2018","journal-title":"Starch\/St\u00e4rke"},{"key":"ref_119","doi-asserted-by":"crossref","first-page":"272","DOI":"10.1016\/j.ijbiomac.2018.04.186","article-title":"Preparation and characterization of starch-based composite films reinforced by cellulose nanofibers","volume":"116","author":"Fazeli","year":"2018","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_120","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/j.jcis.2021.03.010","article-title":"Robust multiphase and multilayer starch\/polymer (TPS\/PBAT) film with simultaneous oxygen\/moisture barrier properties","volume":"593","author":"Chang","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"ref_121","doi-asserted-by":"crossref","first-page":"304","DOI":"10.1016\/j.ijbiomac.2020.07.083","article-title":"Enhancing the functionality of chitosan- and alginate-based active edible coatings\/films for the preservation of fruits and vegetables: A review","volume":"164","author":"Nair","year":"2020","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_122","doi-asserted-by":"crossref","first-page":"196","DOI":"10.1016\/j.tifs.2020.01.002","article-title":"Chitosan based nanocomposite films and coatings: Emerging antimicrobial food packaging alternatives","volume":"97","author":"Kumar","year":"2020","journal-title":"Trends Food Sci. Technol."},{"key":"ref_123","doi-asserted-by":"crossref","first-page":"1636","DOI":"10.1016\/j.ijbiomac.2017.02.008","article-title":"Influence of chitosan concentration on mechanical and barrier properties of corn starch\/chitosan films","volume":"105","author":"Ren","year":"2017","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"117009","DOI":"10.1016\/j.carbpol.2020.117009","article-title":"Preparation of a novel biodegradable packaging film based on corn starch-chitosan and poloxamers","volume":"251","year":"2021","journal-title":"Carbohydr. Polym."},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1007\/s12393-020-09227-y","article-title":"The effects of novel thermal and nonthermal technologies on the properties of edible food packaging","volume":"12","author":"Beikzadeh","year":"2020","journal-title":"Food Eng. Rev."},{"key":"ref_126","doi-asserted-by":"crossref","unstructured":"de Carvalho-Guimar\u00e3es, F.B., Correa, K.L., de Souza, T.P., Rodriguez Amado, J.R., Ribeiro-Costa, R.M., and Silva-J\u00fanior, J.O.C. (2022). A review of Pickering emulsions: Perspectives and applications. Pharmaceuticals, 15.","DOI":"10.3390\/ph15111413"},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"5044","DOI":"10.1080\/10408398.2021.2012420","article-title":"Ultrasonication effects on physicochemical properties of biopolymer-based films: A comprehensive review","volume":"63","author":"Mi","year":"2023","journal-title":"Crit. Rev. Food Sci. Nutr."},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"140269","DOI":"10.1016\/j.foodchem.2024.140269","article-title":"Investigation of film physical properties under various starch thermal treatments with emphasis on retrogradation effects","volume":"458","author":"Xu","year":"2024","journal-title":"Food Chem."},{"key":"ref_129","doi-asserted-by":"crossref","unstructured":"Basiak, E., Lenart, A., and Debeaufort, F. (2018). How glycerol and water contents affect the structural and functional properties of starch-based edible films. Polymers, 10.","DOI":"10.3390\/polym10040412"},{"key":"ref_130","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/j.ijbiomac.2021.06.099","article-title":"Effect of plasticizers on physical, thermal, and tensile properties of thermoplastic films based on Dioscorea hispida starch","volume":"185","author":"Hazrati","year":"2021","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_131","doi-asserted-by":"crossref","unstructured":"Qin, Y., Wang, W., Zhang, H., Dai, Y., Hou, H., and Dong, H. (2019). Effects of Citric Acid on Structures and Properties of Thermoplastic Hydroxypropyl Amylomaize Starch Films. Materials, 12.","DOI":"10.3390\/ma12091565"},{"key":"ref_132","doi-asserted-by":"crossref","first-page":"125478","DOI":"10.1016\/j.ijbiomac.2023.125478","article-title":"Thermoplastic starch\/polyvinyl alcohol blends modification by citric acid\u2013glycerol polyesters","volume":"244","author":"Castro","year":"2023","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_133","doi-asserted-by":"crossref","unstructured":"Djafari Petroudy, S.R., Chabot, B., Loranger, E., Naebe, M., Shojaeiarani, J., Gharehkhani, S., Ahvazi, B., Hu, J., and Thomas, S. (2021). Recent Advances in Cellulose Nanofibers Preparation through Energy-Efficient Approaches: A Review. Energies, 14.","DOI":"10.3390\/en14206792"},{"key":"ref_134","doi-asserted-by":"crossref","first-page":"161257","DOI":"10.1016\/j.cej.2025.161257","article-title":"Energy and property trade-offs in nanocellulose production: High-pressure homogenization at different processing consistencies","volume":"509","author":"Aguado","year":"2025","journal-title":"Chem. Eng. J."},{"key":"ref_135","doi-asserted-by":"crossref","first-page":"11056","DOI":"10.1021\/acssuschemeng.4c04198","article-title":"Biodegradable starch-based nanocomposite films with exceptional water and oxygen barrier properties","volume":"12","author":"Dong","year":"2024","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_136","unstructured":"(2004). Regulation (EC) No 1935\/2004 of the European Parliament and of the Council of 27 October 2004 on materials and articles intended to come into contact with food. Off. J. Eur. Union, L338, 4\u201317."}],"container-title":["Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4360\/18\/4\/490\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,22]],"date-time":"2026-02-22T05:10:32Z","timestamp":1771737032000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4360\/18\/4\/490"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,15]]},"references-count":136,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2026,2]]}},"alternative-id":["polym18040490"],"URL":"https:\/\/doi.org\/10.3390\/polym18040490","relation":{},"ISSN":["2073-4360"],"issn-type":[{"value":"2073-4360","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,15]]}}}