{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T14:25:22Z","timestamp":1775831122296,"version":"3.50.1"},"reference-count":84,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2022,7,7]],"date-time":"2022-07-07T00:00:00Z","timestamp":1657152000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"FP7 European program","award":["ERANETMED_ENERG-065"],"award-info":[{"award-number":["ERANETMED_ENERG-065"]}]},{"name":"FP7 European program","award":["02\/2016"],"award-info":[{"award-number":["02\/2016"]}]},{"name":"FP7 European program","award":["UIDB\/00100\/2020"],"award-info":[{"award-number":["UIDB\/00100\/2020"]}]},{"name":"FP7 European program","award":["UIDP\/00100\/2020"],"award-info":[{"award-number":["UIDP\/00100\/2020"]}]},{"name":"FP7 European program","award":["2020.00030.CEECIND"],"award-info":[{"award-number":["2020.00030.CEECIND"]}]},{"name":"UOBRC","award":["ERANETMED_ENERG-065"],"award-info":[{"award-number":["ERANETMED_ENERG-065"]}]},{"name":"UOBRC","award":["02\/2016"],"award-info":[{"award-number":["02\/2016"]}]},{"name":"UOBRC","award":["UIDB\/00100\/2020"],"award-info":[{"award-number":["UIDB\/00100\/2020"]}]},{"name":"UOBRC","award":["UIDP\/00100\/2020"],"award-info":[{"award-number":["UIDP\/00100\/2020"]}]},{"name":"UOBRC","award":["2020.00030.CEECIND"],"award-info":[{"award-number":["2020.00030.CEECIND"]}]},{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","award":["ERANETMED_ENERG-065"],"award-info":[{"award-number":["ERANETMED_ENERG-065"]}]},{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","award":["02\/2016"],"award-info":[{"award-number":["02\/2016"]}]},{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","award":["UIDB\/00100\/2020"],"award-info":[{"award-number":["UIDB\/00100\/2020"]}]},{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","award":["UIDP\/00100\/2020"],"award-info":[{"award-number":["UIDP\/00100\/2020"]}]},{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","award":["2020.00030.CEECIND"],"award-info":[{"award-number":["2020.00030.CEECIND"]}]},{"name":"M.C. Bacariza contract","award":["ERANETMED_ENERG-065"],"award-info":[{"award-number":["ERANETMED_ENERG-065"]}]},{"name":"M.C. Bacariza contract","award":["02\/2016"],"award-info":[{"award-number":["02\/2016"]}]},{"name":"M.C. Bacariza contract","award":["UIDB\/00100\/2020"],"award-info":[{"award-number":["UIDB\/00100\/2020"]}]},{"name":"M.C. Bacariza contract","award":["UIDP\/00100\/2020"],"award-info":[{"award-number":["UIDP\/00100\/2020"]}]},{"name":"M.C. Bacariza contract","award":["2020.00030.CEECIND"],"award-info":[{"award-number":["2020.00030.CEECIND"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Processes"],"abstract":"<jats:p>As the utilization of zeolites has become more frequent in the dry reforming of methane (DRM) reaction, more systematic studies are required to evaluate properly the influence of zeolites\u2019 composition and framework type on the performance. Therefore, in this work, a step-by-step study was performed with the aim of analyzing the effects of Ni loading (5, 10 or 15 wt.% over USY(3) zeolite), Si\/Al ratio (3, 15 or 38 on USY zeolites with 15 wt.% Ni) and framework type (USY, BEA, ZSM-5 or MOR for 15 wt.% Ni and Si\/Al ratios of \u224840) on catalysts\u2019 properties and performances. Increasing Ni loadings enhanced CH4 and CO2 conversions even though the catalysts\u2019 stability was decreasing over the time. The variation of the Si\/Al ratio on USY and the use of different zeolites had also a remarkable impact on the catalytic performance. For instance, at 500\u2013600 \u00b0C reaction temperatures, the catalysts with higher basicity and reducibility exhibited the best results. However, when the temperature was further increased, catalysts presenting stronger metal\u2013support interactions (nickel nanoparticles located in mesoporous cavities) displayed the highest conversions and stability over time. In brief, the use of 15 wt.% Ni and a USY zeolite, with both micro- and mesopores and high surface area, led to the best performances, mainly attributed to a favorable number of Ni0 active sites and the establishment of stronger metal\u2013support interactions (due to nanoparticles confinement inside the mesopores).<\/jats:p>","DOI":"10.3390\/pr10071331","type":"journal-article","created":{"date-parts":[[2022,7,7]],"date-time":"2022-07-07T22:11:47Z","timestamp":1657231907000},"page":"1331","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Carbon Dioxide Reforming of Methane over Nickel-Supported Zeolites: A Screening Study"],"prefix":"10.3390","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4236-6724","authenticated-orcid":false,"given":"Carmen","family":"Bacariza","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural (CQE), Departamento de Engenharia Qu\u00edmica, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049 001 Lisboa, Portugal"}]},{"given":"Leila","family":"Karam","sequence":"additional","affiliation":[{"name":"Laboratoire de R\u00e9activit\u00e9 de Surface, Campus Pierre et Marie Curie, Sorbonne Universit\u00e9, UMR CNRS 7197, 4 Place Jussieu, 75005 Paris, France"},{"name":"Department of Chemical Engineering, Faculty of Engineering, University of Balamand, Amioun P.O. Box 33, El Koura, Lebanon"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7340-8969","authenticated-orcid":false,"given":"Nissrine","family":"El Hassan","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Faculty of Engineering, University of Balamand, Amioun P.O. Box 33, El Koura, Lebanon"},{"name":"Petroleum Engineering Program, School of Engineering, Lebanese American University, Byblos P.O. Box 36, Lebanon"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9830-7160","authenticated-orcid":false,"given":"Jos\u00e9 M.","family":"Lopes","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural (CQE), Departamento de Engenharia Qu\u00edmica, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049 001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5878-5742","authenticated-orcid":false,"given":"Carlos","family":"Henriques","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural (CQE), Departamento de Engenharia Qu\u00edmica, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049 001 Lisboa, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,7,7]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"11631","DOI":"10.1007\/s11356-019-04767-1","article-title":"Evaluation of Biogas Upgrading Technologies and Future Perspectives: A Review","volume":"26","author":"Kapoor","year":"2019","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_2","unstructured":"Minh, D.P., Siang, T.J., Vo, D.-V.N., Phan, T.S., Ridart, C., Nzihou, A., and Grouset, D. (2018). Hydrogen Production from Biogas Reforming: An Overview of Steam Reforming, Dry Reforming, Dual Reforming, and Tri-Reforming of Methane, Elsevier."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"567","DOI":"10.1007\/s13399-019-00417-1","article-title":"Dry Reforming of Methane Using Various Catalysts in the Process: Review","volume":"10","author":"Singh","year":"2019","journal-title":"Biomass. Conv. 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