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Biomass from agroforestry and agricultural wastes is the richest natural carbon source and a sustainable option for woody biomass from a circular economic perspective. The European Union (EU) is estimated to produce 1.3 billion tons of agri-food waste annually. Portugal has a large supply of residual biomass, as well as other byproducts and wastes from forestry, agriculture, and the food industry, and has a high availability of residual biomass. By using biomass waste to create high-value products, Portugal envisages an improvement in its economic performance, while reducing its dependence on energy imports and fossil fuel use. This review explores the potential of agri-food waste obtained from Portuguese industries through thermochemical conversion technologies as a promising sustainable substitute for wood-based biomass for the development of eco-friendly biofuels, biochemicals, and high-value carbonaceous materials, and their applications. This strategy, based on the circular bioeconomy concept, can help reduce reliance on fossil fuels, reduce greenhouse gas emissions, fulfil the needs of the growing population, and offer a sustainable waste management solution.<\/jats:p>","DOI":"10.3390\/pr11102870","type":"journal-article","created":{"date-parts":[[2023,9,29]],"date-time":"2023-09-29T05:48:13Z","timestamp":1695966493000},"page":"2870","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Management of Agri-Food Waste Based on Thermochemical Processes towards a Circular Bioeconomy Concept: The Case Study of the Portuguese Industry"],"prefix":"10.3390","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1762-1175","authenticated-orcid":false,"given":"Cristina V.","family":"Berenguer","sequence":"first","affiliation":[{"name":"CQM\u2014Centro de Qu\u00edmica da Madeira, NPRG, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7223-1022","authenticated-orcid":false,"given":"Rosa","family":"Perestrelo","sequence":"additional","affiliation":[{"name":"CQM\u2014Centro de Qu\u00edmica da Madeira, NPRG, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0316-5348","authenticated-orcid":false,"given":"Jorge A. M.","family":"Pereira","sequence":"additional","affiliation":[{"name":"CQM\u2014Centro de Qu\u00edmica da Madeira, NPRG, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1965-3151","authenticated-orcid":false,"given":"Jos\u00e9 S.","family":"C\u00e2mara","sequence":"additional","affiliation":[{"name":"CQM\u2014Centro de Qu\u00edmica da Madeira, NPRG, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal"},{"name":"Departamento de Qu\u00edmica, Faculdade de Ci\u00eancias Exatas e Engenharia, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2023,9,29]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"969","DOI":"10.1016\/j.enconman.2009.11.038","article-title":"Overview of recent advances in thermo-chemical conversion of biomass","volume":"51","author":"Zhang","year":"2010","journal-title":"Energy Convers. 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