{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:04:51Z","timestamp":1760144691345,"version":"build-2065373602"},"reference-count":40,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2024,4,29]],"date-time":"2024-04-29T00:00:00Z","timestamp":1714348800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Science, Technological Development and Innovation of the Republic of Serbia","award":["451-03-65\/2024-03\/200146, 451-03-66\/2024-03\/200146, 451-03-65\/2024-03\/200116"],"award-info":[{"award-number":["451-03-65\/2024-03\/200146, 451-03-66\/2024-03\/200146, 451-03-65\/2024-03\/200116"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Processes"],"abstract":"<jats:p>An ion-exchange procedure of synthetic zeolite ZSM-5 (Si\/Al = 15) was used to prepare three cobalt ZSM-5 zeolites (CoM-ZSM5 (M = Zn and Ni)) that were examined for OERs in alkaline media. The structural, morphological, and surface properties of the prepared materials were studied by X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy with energy dispersive spectroscopy, and low-temperature nitrogen adsorption. All three electrocatalysts showed OER activity where CoNi-ZSM5 presented the highest current density (9.5 mA cm\u22122 at 2 V), the lowest Tafel slope (134 mV dec\u22121), and the lowest resistances of the charge transfer reaction (31.5 \u03a9). Overpotential (\u03b7onset) at an onset potential of 410 mV for both CoNi-ZSM5 and Co-ZSM5 and 440 mV for CoZn-ZSM5 electrodes was observed. Co-ZSM5 showed somewhat lower OER catalytic activity than CoNi-ZSM5, while CoZn-ZSM5 demonstrated the lowest OER catalytic activity. The Rct of CoZn-ZSM5 is significantly higher than the Rct of CoNi-ZSM5, which could lead to their different OER activities. Good OER stability and low price are the main advantages of the synthesized CoM-ZSM5 samples in this study.<\/jats:p>","DOI":"10.3390\/pr12050907","type":"journal-article","created":{"date-parts":[[2024,5,2]],"date-time":"2024-05-02T08:42:57Z","timestamp":1714639377000},"page":"907","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["CoM-ZSM5 (M = Zn and Ni) Zeolites for an Oxygen Evolution Reaction in Alkaline Media"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2266-6738","authenticated-orcid":false,"given":"Jadranka","family":"Miliki\u0107","sequence":"first","affiliation":[{"name":"Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11158 Belgrade, Serbia"}]},{"given":"Srna","family":"Stojanovi\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11158 Belgrade, Serbia"}]},{"given":"Katarina","family":"Rondovi\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11158 Belgrade, Serbia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7858-235X","authenticated-orcid":false,"given":"Ljiljana","family":"Damjanovi\u0107-Vasili\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11158 Belgrade, Serbia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2790-3950","authenticated-orcid":false,"given":"Vladislav","family":"Rac","sequence":"additional","affiliation":[{"name":"Faculty of Agriculture, University of Belgrade, Nemanjina 6, 11080 Belgrade, Serbia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0203-4012","authenticated-orcid":false,"given":"Biljana","family":"\u0160ljuki\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11158 Belgrade, Serbia"},{"name":"Center of Physics and Engineering of Advanced Materials, Laboratory for Physics of Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2024,4,29]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"106830","DOI":"10.1016\/j.catcom.2023.106830","article-title":"CoSe2@Co3O4 nanostructures: A promising catalyst for oxygen evolution reaction in alkaline media","volume":"186","author":"Hanan","year":"2023","journal-title":"Catal. Commun."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"124133","DOI":"10.1016\/j.jssc.2023.124133","article-title":"Copper-cobalt bimetallic conductive metal\u2013organic frameworks as bifunctional oxygen electrocatalyst in alkaline and neutral media","volume":"325","author":"Zhang","year":"2023","journal-title":"J. Solid State Chem."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"100914","DOI":"10.1016\/j.mtchem.2022.100914","article-title":"Controllable preparation of nickel phosphide using iron and cobalt as electrocatalyst for hydrogen evolution reaction in alkaline media","volume":"24","author":"Wang","year":"2022","journal-title":"Mater. Today Chem."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"122444","DOI":"10.1016\/j.apcatb.2023.122444","article-title":"Spherical nickel doped cobalt phosphide as an anode catalyst for oxygen evolution reaction in alkaline media: From catalysis to system","volume":"327","author":"Park","year":"2023","journal-title":"Appl. Catal. B Environ."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"399","DOI":"10.1021\/jz2016507","article-title":"Synthesis and activities of rutile IrO2 and RuO2 nanoparticles for oxygen evolution in acid and alkaline solutions","volume":"3","author":"Lee","year":"2012","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"16786","DOI":"10.1016\/j.ijhydene.2012.08.087","article-title":"Zeolite-templated IrxRu1-xO2 electrocatalysts for oxygen evolution reaction in solid polymer electrolyte water electrolyzers","volume":"37","author":"Li","year":"2012","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1016\/j.jiec.2023.03.062","article-title":"Fe-doped Co3O4 nanostructures prepared via hard-template method and used for the oxygen evolution reaction in alkaline media","volume":"123","author":"Kim","year":"2023","journal-title":"J. Ind. Eng. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"111661","DOI":"10.1016\/j.inoche.2023.111661","article-title":"Enhanced cobalt MOF electrocatalyst for oxygen evolution reaction via morphology regulation","volume":"158","author":"Du","year":"2023","journal-title":"Inorg. Chem. Commun."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.jpowsour.2015.11.050","article-title":"High performance and bifunctional cobalt-embedded nitrogen doped carbon\/nanodiamond electrocatalysts for oxygen reduction and oxygen evolution reactions in alkaline media","volume":"305","author":"Wu","year":"2016","journal-title":"J. Power Sources"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"100717","DOI":"10.1016\/j.mtsust.2024.100717","article-title":"Cobalt decorated S-doped carbon electrocatalyst assembly for enhanced oxygen evolution reaction","volume":"26","author":"Mathi","year":"2024","journal-title":"Mater. Today Sustain."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"18977","DOI":"10.1016\/j.ijhydene.2018.08.063","article-title":"NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media","volume":"43","author":"Amaral","year":"2018","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"28337","DOI":"10.1016\/j.ijhydene.2020.07.194","article-title":"Novel 13X Zeolite\/PANI electrocatalyst for hydrogen and oxygen evolution reaction","volume":"45","author":"Vinodh","year":"2020","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"117231","DOI":"10.1016\/j.synthmet.2022.117231","article-title":"Efficient bifunctional cerium-zeolite electrocatalysts for oxygen evolution and oxygen reduction reactions in alkaline media","volume":"292","year":"2023","journal-title":"Synth. Met."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1016\/j.jcis.2021.02.015","article-title":"Bimetal zeolite imidazolate framework derived Mo0.84Ni0.16-Mo2C@NC nanosphere for overall water splitting in alkaline solution","volume":"592","author":"Li","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"141548","DOI":"10.1016\/j.electacta.2022.141548","article-title":"Bimetallic zeolite imidazolium framework derived multiphase Co\/HNC as pH-universal catalysts with efficient oxygen reduction performance for microbial fuel cells","volume":"438","author":"Ding","year":"2023","journal-title":"Electrochim. Acta"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"117668","DOI":"10.1016\/j.jelechem.2023.117668","article-title":"Porous cerium-zeolite bifunctional ORR\/OER electrocatalysts in alkaline media","volume":"944","year":"2023","journal-title":"J. Electroanal. Chem."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"33028","DOI":"10.1016\/j.ijhydene.2020.09.058","article-title":"ZIF-L-Co@carbon fiber paper composite derived Co\/Co3O4@C electrocatalyst for ORR in alkali\/acidic media and overall seawater splitting","volume":"45","author":"Zhang","year":"2020","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"215397","DOI":"10.1016\/j.ccr.2023.215397","article-title":"The universal zeolite ZSM-5: Structure and synthesis strategies. A review","volume":"496","author":"Bensafi","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"ref_19","unstructured":"Baerlocher, C., McCusker, L.B., and Olson, D.H. (2007). Atlas of Zeolite Framework Types, Elsevier Science. [6th ed.]."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"134934","DOI":"10.1016\/j.matlet.2023.134934","article-title":"Desilicated zeolite ZSM-5 based composite polymer electrolytes for solid-state lithium metal batteries","volume":"351","author":"Tao","year":"2023","journal-title":"Mater. Lett."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"406","DOI":"10.1016\/j.micromeso.2016.02.006","article-title":"Zeolite coated polypropylene separators with tunable surface properties for lithium-ion batteries","volume":"226","author":"Dong","year":"2016","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"11609","DOI":"10.1039\/D0CC03976D","article-title":"Nanozeolite ZSM-5 electrolyte additive for long life sodium-ion batteries","volume":"56","author":"Chen","year":"2020","journal-title":"Chem. Commun."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"709","DOI":"10.1016\/j.ssi.2006.01.032","article-title":"PVDF-PEO\/ZSM-5 based composite microporous polymer electrolyte with novel pore configuration and ionic conductivity","volume":"177","author":"Xi","year":"2006","journal-title":"Solid State Ionics"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"753","DOI":"10.1016\/j.memsci.2018.07.056","article-title":"Polymers\/zeolite nanocomposite membranes with enhanced thermal and electrochemical performances for lithium-ion batteries","volume":"564","author":"Zhang","year":"2018","journal-title":"J. Memb. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"3573","DOI":"10.1021\/ic901814f","article-title":"Transition-Metal Ions in Zeolites: Coordination and Activation of Oxygen","volume":"49","author":"Smeets","year":"2010","journal-title":"Inorg. Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"H1013","DOI":"10.1149\/2.0021816jes","article-title":"12-phosphotungstic Acid Supported on BEA Zeolite Composite with Carbonized Polyaniline for Electroanalytical Sensing of Phenols in Environmental Samples","volume":"165","year":"2018","journal-title":"J. Electrochem. Soc."},{"key":"ref_27","unstructured":"Karge, H.G., and Geidel, E. (2004). Molecular Sieves\u2014Characterization I, Springer."},{"key":"ref_28","unstructured":"Rouquerol, F., Rouquerol, J., and Sing, K. (1999). Adsorption by Powders and Porous Solids, Elsevier."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"115842","DOI":"10.1016\/j.jelechem.2021.115842","article-title":"Why shouldn\u2019t double-layer capacitance (Cdl) be always trusted to justify Faradaic electrocatalytic activity differences?","volume":"903","author":"Anantharaj","year":"2021","journal-title":"J. Electroanal. Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1021\/acs.chemmater.6b02796","article-title":"Measurement techniques for the study of thin film heterogeneous water oxidation electrocatalysts","volume":"29","author":"Stevens","year":"2017","journal-title":"Chem. Mater."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1301","DOI":"10.1002\/cssc.201301019","article-title":"Water oxidation by amorphous cobalt-based oxides: Volume activity and proton transfer to electrolyte bases","volume":"7","author":"Klingan","year":"2014","journal-title":"ChemSusChem"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"3068","DOI":"10.1039\/C5TA07586F","article-title":"Benchmarking nanoparticulate metal oxide electrocatalysts for the alkaline water oxidation reaction","volume":"4","author":"Jung","year":"2016","journal-title":"J. Mater. Chem. A"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"13737","DOI":"10.1039\/c3cp51213d","article-title":"Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes","volume":"15","author":"Doyle","year":"2013","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"286","DOI":"10.1016\/j.jechem.2023.08.039","article-title":"Co-Ru alloy nanoparticles decorated onto two-dimensional nitrogen doped carbon nanosheets towards hydrogen\/oxygen evolution reaction and oxygen reduction reaction","volume":"87","author":"Wang","year":"2023","journal-title":"J. Energy Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"51437","DOI":"10.1021\/acsami.0c14521","article-title":"Ultralow Ru-Induced Bimetal Electrocatalysts with a Ru-Enriched and Mixed-Valence Surface Anchored on a Hollow Carbon Matrix for Oxygen Reduction and Water Splitting","volume":"12","author":"Li","year":"2020","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"232692","DOI":"10.1016\/j.jpowsour.2023.232692","article-title":"Molten-salt confined synthesis of nitrogen-doped carbon nanosheets supported Co3O4 nanoparticles as a superior oxygen electrocatalyst for rechargeable Zn-air battery","volume":"560","author":"Xi","year":"2023","journal-title":"J. Power Sources"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1244148","DOI":"10.3389\/fchem.2023.1244148","article-title":"Effect of carbon support on the activity of monodisperse Co45Pt55 nanoparticles for oxygen evolution in alkaline media","volume":"11","author":"Sevim","year":"2023","journal-title":"Front. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"384","DOI":"10.1179\/174329406X126735","article-title":"Validation of titanium corrosion impedance data using Kramers\u2013Kronig relationships","volume":"22","author":"Bastidas","year":"2006","journal-title":"Surf. Eng."},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"Zhong, H., Campos-Rold\u00e1n, C.A., Zhao, Y., Zhang, S., Feng, Y., and Alonso-Vante, N. (2018). Recent advances of cobalt-based electrocatalysts for oxygen electrode reactions and hydrogen evolution reaction. Catalysts, 8.","DOI":"10.3390\/catal8110559"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"15353","DOI":"10.1021\/ja401797v","article-title":"Reaction pathways for oxygen evolution promoted by cobalt catalyst","volume":"135","author":"Mattioli","year":"2013","journal-title":"J. Am. Chem. Soc."}],"container-title":["Processes"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2227-9717\/12\/5\/907\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T14:36:00Z","timestamp":1760106960000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2227-9717\/12\/5\/907"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4,29]]},"references-count":40,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2024,5]]}},"alternative-id":["pr12050907"],"URL":"https:\/\/doi.org\/10.3390\/pr12050907","relation":{},"ISSN":["2227-9717"],"issn-type":[{"type":"electronic","value":"2227-9717"}],"subject":[],"published":{"date-parts":[[2024,4,29]]}}}