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However, self-assembly of such cyclic\n            <jats:italic>\u03c0<\/jats:italic>\n            -molecules to form organized nanostructures has been rarely explored despite intensive studies on their chemical synthesis. Here we synthesized a family of new cycloparaphenylenes and found that these fully hydrophobic and nonplanar cyclic\n            <jats:italic>\u03c0<\/jats:italic>\n            -molecules could self-assemble into structurally distinct two-dimensional crystalline multilayer nanosheets. Moreover, these crystalline multilayer nanosheets could overcome inherent rigidity to curve into closed crystalline vesicles in solution. These supramolecular assemblies show that the cyclic molecular scaffolds are homogeneously arranged on the surface of nanosheets and vesicles with their molecular isotropic x-y plane standing obliquely on the surface. These supramolecular architectures that combined exact crystalline order, orientation-specific arrangement of\n            <jats:italic>\u03c0<\/jats:italic>\n            -conjugated cycles, controllable morphology, uniform molecular pore, superior florescence quench ability, and photoluminescence are expected to give rise to a new class of functional materials displaying unique photonic, electronic, and biological functions.\n          <\/jats:p>","DOI":"10.34133\/2019\/1953926","type":"journal-article","created":{"date-parts":[[2019,7,28]],"date-time":"2019-07-28T23:45:07Z","timestamp":1564357507000},"source":"Crossref","is-referenced-by-count":6,"title":["Nanoscale Crystalline Sheets and Vesicles Assembled from Nonplanar Cyclic\n            <i>\u03c0<\/i>\n            -Conjugated Molecules"],"prefix":"10.34133","volume":"2019","author":[{"given":"Huang","family":"Tang","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of High Performance Polymer Materials and Technolog, and Department of Polymer Science &amp; Engineering, College of Chemistry &amp; Chemical Engineering, Nanjing University, Nanjing, 210093, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhewei","family":"Gu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of High Performance Polymer Materials and Technolog, and Department of Polymer Science &amp; Engineering, College of Chemistry &amp; Chemical Engineering, Nanjing University, Nanjing, 210093, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Haifeng","family":"Ding","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing, 210093, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhibo","family":"Li","sequence":"additional","affiliation":[{"name":"School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shiyan","family":"Xiao","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Soft Matter Chemistry and Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, 230026, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Wu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of High Performance Polymer Materials and Technolog, and Department of Polymer Science &amp; Engineering, College of Chemistry &amp; Chemical Engineering, Nanjing University, Nanjing, 210093, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiqun","family":"Jiang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of High Performance Polymer Materials and Technolog, and Department of Polymer Science &amp; Engineering, College of Chemistry &amp; Chemical Engineering, Nanjing University, Nanjing, 210093, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"221","published-online":{"date-parts":[[2019,7,28]]},"reference":[{"doi-asserted-by":"publisher","key":"e_1_3_5_1_2","DOI":"10.1021\/acs.chemrev.5b00008"},{"doi-asserted-by":"publisher","key":"e_1_3_5_2_2","DOI":"10.1021\/cr500304f"},{"doi-asserted-by":"publisher","key":"e_1_3_5_3_2","DOI":"10.1038\/ncomms11118"},{"issue":"1","key":"e_1_3_5_4_2","doi-asserted-by":"crossref","first-page":"535","DOI":"10.1126\/science.1222453","article-title":"Carbon nanotubes: present and future commercial applications","volume":"339","author":"de Volder M. 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Jasti, \u201cThe dynamic, size-dependent properties of [5]-[12]cycloparaphenylenes,\u201d Chemical Society Reviews , vol. 44, no. 18, pp. 6401\u20136410, 2015","journal-title":"Chemical Society Reviews"},{"issue":"51","key":"e_1_3_5_21_2","doi-asserted-by":"crossref","first-page":"13722","DOI":"10.1002\/anie.201306881","article-title":"Isolation and characterization of the cycloparaphenylene radical cation and dication","volume":"52","author":"Kayahara E.","year":"2013","unstructured":"E. Kayahara, T. Kouyama, T. Kato, H. Takaya, N. Yasuda, and S. 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