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Here, we report a leech-inspired cellulosic elastomer constructed from cellulose, diatomite, and polyacrylamide through ethanol-induced structural reconstruction. The resulting bioinspired elastomer exhibits enhanced mechanical performance and efficient energy dissipation, with nearly complete compressive recoverability, a compressive strength above 90 MPa, and a load-bearing capacity exceeding 160,000 times its own weight. The elastomer further demonstrates high resistance to static puncture and dynamic impact, with a puncture resistance energy of 304.22 mJ and an impact toughness of 28.62 MJ m\n                    <jats:sup>\u22123<\/jats:sup>\n                    , while maintaining self-healing capability without thermal treatment and tolerance to ultralow temperatures down to \u2212196 \u00b0C. In addition, the elastomer is compatible with roll-to-roll manufacturing and can be produced at the meter scale at a low cost. This work offers a scalable strategy for fabricating robust elastomers with potential applications in advanced impact protection and emerging soft technologies.\n                  <\/jats:p>","DOI":"10.34133\/research.1460","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T06:44:32Z","timestamp":1790837072000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark_01","source":"Crossref","is-referenced-by-count":0,"title":["A Bioinspired Cellulosic Elastomer with Ultrahigh Robustness Enabled by Structure-Induced Reconstruction for Impact Protection"],"prefix":"10.34133","volume":"9","author":[{"given":"Geyuan","family":"Jiang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering, \rShenyang University of Technology, Shenyang, Liaoning, China."},{"name":"Key Laboratory on Resources Chemicals and Materials of Ministry of Education, \rShenyang University of Chemical Technology, Shenyang, Liaoning, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minxin","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory on Resources Chemicals and Materials of Ministry of Education, \rShenyang University of Chemical Technology, Shenyang, Liaoning, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangwen","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering, \rShenyang University of Technology, Shenyang, Liaoning, China."},{"name":"Key Laboratory on Resources Chemicals and Materials of Ministry of Education, \rShenyang University of Chemical Technology, Shenyang, Liaoning, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2813-7263","authenticated-orcid":true,"given":"Dawei","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory on Resources Chemicals and Materials of Ministry of Education, \rShenyang University of Chemical Technology, Shenyang, Liaoning, China."},{"name":"Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, \rNortheast Forestry University, Harbin, Heilongjiang, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0634-7913","authenticated-orcid":true,"given":"Haipeng","family":"Yu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, \rNortheast Forestry University, Harbin, Heilongjiang, China."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"e_1_3_4_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c06945"},{"issue":"1","key":"e_1_3_4_3_2","first-page":"198","article-title":"Electric-double-layer-gated 2D transistors for bioinspired sensors and neuromorphic devices","volume":"15","author":"Lin X","year":"2024","unstructured":"Lin X, Li Y, Lei Y, Sun Q. 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