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Nanotechnol."],"accepted":{"date-parts":[[2020,2,27]]},"abstract":"<jats:p>MoO<jats:sub>3<\/jats:sub> is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO<jats:sub>3<\/jats:sub> arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of MoO<jats:sub>3<\/jats:sub> is carried out in 2-butanone for the first time. The achieved concentration of the dispersion is about 0.57 mg\u00b7mL<jats:sup>\u22121<\/jats:sup> with a yield of 5.7%, which are the highest values reported to date. These high values of concentration and yield can be attributed to a favorable matching of energies involved in exfoliation and stabilization of MoO<jats:sub>3<\/jats:sub> nanosheets in 2-butanone. Interestingly, the MoO<jats:sub>3<\/jats:sub> dispersion in 2-butanone retains its intrinsic nature even after exposure to sunlight for 24 h. The composites of MoO<jats:sub>3<\/jats:sub> nanosheets were used as an electrode material for supercapacitors and showed a high specific capacitance of 201 F\u00b7g<jats:sup>\u22121<\/jats:sup> in a three-electrode configuration at a scan rate of 50 mV\u00b7s<jats:sup>\u22121<\/jats:sup>.<\/jats:p>","DOI":"10.3762\/bjnano.11.52","type":"journal-article","created":{"date-parts":[[2020,4,17]],"date-time":"2020-04-17T09:40:41Z","timestamp":1587116441000},"page":"662-670","source":"Crossref","is-referenced-by-count":11,"title":["Exfoliation in a low boiling point solvent and electrochemical applications of MoO<sub>3<\/sub>"],"prefix":"10.3762","volume":"11","author":[{"given":"Matangi","family":"Sricharan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bikesh","family":"Gupta","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1046-447X","authenticated-orcid":false,"given":"Sreejesh","family":"Moolayadukkam","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8279-8447","authenticated-orcid":false,"given":"H S S Ramakrishna","family":"Matte","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"2086","published-online":{"date-parts":[[2020,4,17]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","DOI":"10.1142\/9789814287005_0002"},{"key":"ref2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1226419"},{"key":"ref3","doi-asserted-by":"publisher","DOI":"10.1039\/c6ta02811j"},{"key":"ref4","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702965"},{"key":"ref5","doi-asserted-by":"publisher","DOI":"10.1088\/2053-1583\/4\/1\/015005"},{"key":"ref6","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201701619"},{"key":"ref7","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2005.01.012"},{"key":"ref8","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200901640"},{"key":"ref9","doi-asserted-by":"publisher","DOI":"10.1126\/science.1194975"},{"key":"ref10","doi-asserted-by":"publisher","DOI":"10.1021\/cm500271u"},{"key":"ref12","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b12076"},{"key":"ref13","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201306097"},{"key":"ref14","doi-asserted-by":"publisher","DOI":"10.1039\/c7cp00644f"},{"key":"ref15","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5b02683"},{"key":"ref16","doi-asserted-by":"publisher","DOI":"10.1021\/la201797h"},{"key":"ref17","doi-asserted-by":"publisher","DOI":"10.1039\/c9nr02019e"},{"key":"ref18","doi-asserted-by":"publisher","DOI":"10.1021\/acsaelm.9b00500"},{"key":"ref19","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3213"},{"key":"ref20","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201503834"},{"key":"ref21","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.9b00645"},{"key":"ref22","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2015.02.005"},{"key":"ref23","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201200044"},{"key":"ref24","doi-asserted-by":"publisher","DOI":"10.1002\/adfm201301851"},{"key":"ref25","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13474d"},{"key":"ref26","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2016.12.140"},{"key":"ref27","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2017.03.006"},{"key":"ref28","doi-asserted-by":"publisher","DOI":"10.1021\/jp204036a"},{"key":"ref29","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2015.01.017"},{"key":"ref30","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201300470"},{"key":"ref31","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9503"}],"container-title":["Beilstein Journal of Nanotechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/11\/52","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/content\/pdf\/2190-4286-11-52.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/11\/52","content-type":"text\/html","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,6,25]],"date-time":"2021-06-25T15:52:08Z","timestamp":1624636328000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/11\/52"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,4,17]]},"references-count":30,"URL":"https:\/\/doi.org\/10.3762\/bjnano.11.52","archive":["Portico"],"relation":{},"ISSN":["2190-4286"],"issn-type":[{"value":"2190-4286","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,4,17]]}}}