{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:54:28Z","timestamp":1785405268320,"version":"3.56.0"},"reference-count":50,"publisher":"Beilstein Institut","license":[{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"am","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"name":"State assignment of Federal Scientific Research Center \u00abCrystallography and Photonics\u00bb of Russian Academy of Sciences"},{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["project no. 22-23-00540"],"award-info":[{"award-number":["project no. 22-23-00540"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Beilstein J. Nanotechnol."],"accepted":{"date-parts":[[2023,9,12]]},"abstract":"<jats:p>\n                    This article describes an approach for synthesizing silicon phosphide nanoparticles with a defective zinc blende structure under mild conditions through thermal annealing of hydrogenated silicon nanoparticles with red phosphorus. The synthesized Si\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sub>4<\/jats:sub>\n                    nanoparticles were analyzed using FTIR, XRD, electron diffraction, EDX, TEM, Raman spectroscopy, X-ray fluorescence spectrometry, and UV\u2013vis spectrophotometry. For the isolated cubic Si\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sub>4<\/jats:sub>\n                    phase, a cell parameter of\n                    <jats:italic>a<\/jats:italic>\n                    = 5.04 \u00c5 was determined, and the bandgap was estimated to be equal to 1.25 eV. Because of the nanoscale dimensions of the obtained Si\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sub>4<\/jats:sub>\n                    nanoparticles, the product may exhibit several exceptional properties as a precursor for diffusion doping of wafers and as anode material for Li-ion batteries. A similar method with a hydrogenation step offers the possibility to obtain other compounds, such as silicon selenides, arsenides, and sulfides.\n                  <\/jats:p>","DOI":"10.3762\/bjnano.14.80","type":"journal-article","created":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T08:03:02Z","timestamp":1695715382000},"page":"971-979","source":"Crossref","is-referenced-by-count":1,"title":["Isolation of cubic Si\n                    <sub>3<\/sub>\n                    P\n                    <sub>4<\/sub>\n                    in the form of nanocrystals"],"prefix":"10.3762","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-8813-3894","authenticated-orcid":false,"given":"Polina K","family":"Nikiforova","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000123429668","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3022-4326","authenticated-orcid":false,"given":"Sergei S","family":"Bubenov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000123429668","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vadim B","family":"Platonov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000123429668","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4571-988X","authenticated-orcid":false,"given":"Andrey S","family":"Kumskov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05q51gp63","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8593-2971","authenticated-orcid":false,"given":"Nikolay N","family":"Kononov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/050rg6t21","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000406379699","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tatyana A","family":"Kuznetsova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000123429668","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3820-4853","authenticated-orcid":false,"given":"Sergey G","family":"Dorofeev","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000123429668","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"2086","published-online":{"date-parts":[[2023,9,26]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00644"},{"key":"ref2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-3991(84)90075-5"},{"key":"ref3","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.2c05088"},{"key":"ref4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b11416"},{"key":"ref5","doi-asserted-by":"publisher","DOI":"10.1016\/0038-1101(61)90029-6"},{"key":"ref6","doi-asserted-by":"publisher","DOI":"10.1063\/1.322549"},{"key":"ref7","doi-asserted-by":"publisher","DOI":"10.1063\/1.4942605"},{"key":"ref8","first-page":"763","volume-title":"P-Si. 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