{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T11:22:40Z","timestamp":1788175360018,"version":"build-2803163510"},"reference-count":32,"publisher":"Beilstein Institut","license":[{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"am","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/501100004052","name":"King Abdullah University of Science and Technology","doi-asserted-by":"publisher","award":["Baseline"],"award-info":[{"award-number":["Baseline"]}],"id":[{"id":"10.13039\/501100004052","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Beilstein J. Nanotechnol."],"accepted":{"date-parts":[[2026,8,12]]},"abstract":"<jats:p>\n                    Metallic Ni nanoparticles doped with Mo are recently developed highly active nanocatalysts for dry reforming of methane (DRM). However, the nature of interactions and co-existence of Ni and Mo, optimal Ni\/Mo ratios, as well as the impact of synthetic methods on catalyst structure and activity, remain unclear. This study compares two different synthetic approaches, one-pot synthesis (OP) and post-modification (PM), to determine the optimal Ni\/Mo ratio for catalytic performance. The OP method promotes the formation of NiMo nanoparticles under adequate reducing conditions, significantly enhancing DRM activity. In contrast, the PM method ensures precise Ni\/Mo ratios but leads to the formation of large MoO\n                    <jats:sub>3<\/jats:sub>\n                    nanocrystals that obstruct active sites, thus reducing the catalytic performance. Our findings demonstrate that the highest DRM activity is achieved with a 10:1 molar ratio of Ni\/Mo to predominantly form alloy nanoparticles and emphasize that the synthesis method, along with the stoichiometric ratios, plays a crucial role in achieving exceptional catalytic performance.\n                  <\/jats:p>","DOI":"10.3762\/bjnano.17.84","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T11:09:53Z","timestamp":1788174593000},"page":"1212-1222","source":"Crossref","is-referenced-by-count":0,"title":["Optimization of NiMo alloy nanoparticles for catalytic dry reforming of methane"],"prefix":"10.3762","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3939-7960","authenticated-orcid":false,"given":"Azimet A","family":"Karluk","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q3tbs38","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000119265090","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9159-3336","authenticated-orcid":false,"given":"Javeed","family":"Mahmood","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q3tbs38","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000119265090","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6052-547X","authenticated-orcid":false,"given":"Seok-Jin","family":"Kim","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q3tbs38","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000119265090","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0580-3331","authenticated-orcid":false,"given":"Cafer T","family":"Yavuz","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q3tbs38","id-type":"ROR","asserted-by":"publisher"},{"id":"https:\/\/www.isni.org\/0000000119265090","id-type":"ISNI","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"2086","published-online":{"date-parts":[[2026,8,31]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2022.06.029"},{"key":"ref2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601545"},{"key":"ref3","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c00406"},{"key":"ref4","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah7161"},{"key":"ref5","doi-asserted-by":"publisher","DOI":"10.1039\/d1ta00440a"},{"key":"ref6","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2005.03.011"},{"key":"ref7","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60395d"},{"key":"ref8","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.3c00083"},{"key":"ref9","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.2c00523"},{"key":"ref10","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00357"},{"key":"ref11","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11487"},{"key":"ref12","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03720"},{"key":"ref13","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202100226"},{"key":"ref14","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2017.03.208"},{"key":"ref15","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05737"},{"key":"ref16","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609442"},{"key":"ref17","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav2412"},{"key":"ref18","doi-asserted-by":"publisher","DOI":"10.1126\/science.adp5208"},{"key":"ref19","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02124"},{"key":"ref20","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c03417"},{"key":"ref21","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-025-00715-5"},{"key":"ref22","doi-asserted-by":"publisher","DOI":"10.1039\/d2cp02120j"},{"key":"ref23","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc04596c"},{"key":"ref24","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta12118f"},{"key":"ref25","doi-asserted-by":"publisher","DOI":"10.1039\/c5tc04445f"},{"key":"ref26","doi-asserted-by":"publisher","DOI":"10.1155\/2024\/7724598"},{"key":"ref27","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2021.101678"},{"key":"ref28","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.118626"},{"key":"ref29","doi-asserted-by":"publisher","DOI":"10.1007\/bf00665191"},{"key":"ref30","doi-asserted-by":"publisher","DOI":"10.1039\/d1cy01585k"},{"key":"ref31","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.07.009"},{"key":"ref32","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201600528"}],"container-title":["Beilstein Journal of Nanotechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/17\/84","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/content\/pdf\/2190-4286-17-84.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/17\/84","content-type":"text\/html","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T11:09:53Z","timestamp":1788174593000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/17\/84"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,31]]},"references-count":32,"URL":"https:\/\/doi.org\/10.3762\/bjnano.17.84","archive":["Portico"],"relation":{},"ISSN":["2190-4286"],"issn-type":[{"value":"2190-4286","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,31]]}}}