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Chem."],"accepted":{"date-parts":[[2017,11,16]]},"abstract":"<jats:p>A one-pot three-component route for the synthesis of <jats:italic>S<\/jats:italic>-trifluoromethyl dithiocarbamates by the reaction of secondary amines, carbon disulfide and Togni\u2019s reagent is described. The reactions proceed in moderate to good yields. A similar reaction using a primary aliphatic amine afforded the corresponding isothiocyanate in high yield. A variable temperature NMR study revealed a rotational barrier of 14.6, 18.8, and 15.9 kcal\/mol for the C\u2013N bond in the dithiocarbamate moiety of piperidine, pyrrolidine, and diethylamine adducts, respectively. 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