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Chem."],"accepted":{"date-parts":[[2018,8,28]]},"abstract":"<jats:p>Carbon dioxide (CO<jats:sub>2<\/jats:sub>) is one of the most important materials as renewable chemical feedstock. In this review, the Co- and Rh-catalyzed transformation of CO<jats:sub>2<\/jats:sub> via carbon\u2013carbon bond-forming reactions is summarized. Combinations of metals (cobalt or rhodium), substrates, and reducing agents realize efficient carboxylation reactions using CO<jats:sub>2<\/jats:sub>. The carboxylation of propargyl acetates and alkenyl triflates using cobalt complexes as well as the cobalt-catalyzed reductive carboxylation of \u03b1,\u03b2-unsaturated nitriles and carboxyamides in the presence of Et<jats:sub>2<\/jats:sub>Zn proceed. A Co complex has been demonstrated to act as an efficient catalyst in the carboxylation of allylic C(sp<jats:sup>3<\/jats:sup>)\u2013H bonds. Employing zinc as the reductant, carboxyzincation and the four-component coupling reaction between alkyne, acrylates, CO<jats:sub>2<\/jats:sub>, and zinc occur efficiently. Rh complexes also catalyze the carboxylation of arylboronic esters, C(sp<jats:sup>2<\/jats:sup>)\u2013H carboxylation of aromatic compounds, and hydrocarboxylation of styrene derivatives. 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