{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T03:03:44Z","timestamp":1792119824755,"version":"4.4.0"},"reference-count":41,"publisher":"Beilstein Institut","license":[{"start":{"date-parts":[[2018,2,12]],"date-time":"2018-02-12T00:00:00Z","timestamp":1518393600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2018,2,12]],"date-time":"2018-02-12T00:00:00Z","timestamp":1518393600000},"content-version":"am","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2018,2,12]],"date-time":"2018-02-12T00:00:00Z","timestamp":1518393600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Beilstein J. Org. Chem."],"accepted":{"date-parts":[[2018,1,17]]},"abstract":"<jats:p>We herein report that the regioselective anodic fluorination of <jats:italic>S<\/jats:italic>-alkyl benzothioate and its derivatives in various aprotic solvents using Et<jats:sub>3<\/jats:sub>N\u00b7<jats:italic>n<\/jats:italic>HF (<jats:italic>n<\/jats:italic> = 3\u20135) and Et<jats:sub>4<\/jats:sub>NF\u00b7<jats:italic>n<\/jats:italic>HF (<jats:italic>n<\/jats:italic> = 3\u20135) as supporting electrolyte and a fluorine source successfully provided the corresponding \u03b1-fluorinated products in moderate yields. Dichloromethane containing Et<jats:sub>4<\/jats:sub>NF\u00b74HF was found to be the most suitable combination as electrolytic solvent and supporting salt as well as fluorine source for the anodic fluorination. The electrochemical fluorination of cyclic benzothioates such as benzothiophenone was also achieved.<\/jats:p>","DOI":"10.3762\/bjoc.14.27","type":"journal-article","created":{"date-parts":[[2018,2,12]],"date-time":"2018-02-12T08:38:30Z","timestamp":1518424710000},"page":"389-396","source":"Crossref","is-referenced-by-count":18,"title":["The selective electrochemical fluorination of <i>S<\/i>-alkyl benzothioate and its derivatives"],"prefix":"10.3762","volume":"14","author":[{"given":"Shunsuke","family":"Kuribayashi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomoyuki","family":"Kurioka","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9867-1210","authenticated-orcid":false,"given":"Shinsuke","family":"Inagi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ho-Jung","family":"Lu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biing-Jiun","family":"Uang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Toshio","family":"Fuchigami","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"2086","published-online":{"date-parts":[[2018,2,12]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","DOI":"10.1039\/b610213c"},{"key":"ref2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2002933"},{"key":"ref3","doi-asserted-by":"publisher","DOI":"10.1021\/ja106343h"},{"key":"ref4","doi-asserted-by":"publisher","DOI":"10.1021\/ja2048072"},{"key":"ref5","series-title":"chapter 24","volume-title":"Organic Electrochemistry","author":"Rozhkov","year":"1983","edition":"2"},{"key":"ref6","first-page":"955","author":"Laurent","year":"1986","journal-title":"Bulletin de la Soci\u00e9t\u00e9 Chimique de France"},{"key":"ref7","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)83902-7"},{"key":"ref8","doi-asserted-by":"publisher","DOI":"10.1021\/jo00233a043"},{"key":"ref9","doi-asserted-by":"publisher","DOI":"10.1021\/jo00312a006"},{"key":"ref10","doi-asserted-by":"publisher","DOI":"10.1039\/C39910001027"},{"key":"ref11","series-title":"chapter 25","volume-title":"Organic Electrochemistry","author":"Fuchigami","year":"2001","edition":"4"},{"key":"ref12","doi-asserted-by":"publisher","DOI":"10.1023\/B:JACH.0000016670.97434.c7"},{"key":"ref13","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2003.11.017"},{"key":"ref14","doi-asserted-by":"publisher","DOI":"10.1039\/C1CC12414E"},{"key":"ref15","series-title":"chapter 20","volume-title":"Organic Electrochemistry,","author":"Fuchigami","year":"2015","edition":"5"},{"key":"ref16","doi-asserted-by":"publisher","DOI":"10.1002\/9781118670750.ch05"},{"key":"ref17","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2016.07.016"},{"key":"ref18","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2016.02.051"},{"key":"ref19","doi-asserted-by":"publisher","DOI":"10.1002\/elan.201600130"},{"key":"ref20","doi-asserted-by":"publisher","DOI":"10.1149\/1.1837498"},{"key":"ref21","doi-asserted-by":"publisher","DOI":"10.1016\/S0013-4686(00)00379-0"},{"key":"ref22","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2005.10.010"},{"key":"ref23","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(02)01297-4"},{"key":"ref24","doi-asserted-by":"publisher","DOI":"10.1149\/1.1394102"},{"key":"ref25","doi-asserted-by":"publisher","DOI":"10.1016\/S0013-4686(97)85466-7"},{"key":"ref26","doi-asserted-by":"publisher","DOI":"10.1021\/jo00116a037"},{"key":"ref27","doi-asserted-by":"publisher","DOI":"10.1021\/jo00128a044"},{"key":"ref28","doi-asserted-by":"publisher","DOI":"10.1021\/ol049152f"},{"key":"ref29","doi-asserted-by":"publisher","DOI":"10.1149\/2.1601713jes"},{"key":"ref30","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(02)00559-8"},{"key":"ref31","doi-asserted-by":"publisher","DOI":"10.5012\/bkcs.2003.24.2.243"},{"key":"ref32","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00324"},{"key":"ref33","doi-asserted-by":"publisher","DOI":"10.1021\/ol500459x"},{"key":"ref34","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201201059"},{"key":"ref35","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201501177"},{"key":"ref36","doi-asserted-by":"publisher","DOI":"10.1016\/S0957-4166(96)00463-6"},{"key":"ref37","doi-asserted-by":"publisher","DOI":"10.1248\/cpb.30.440"},{"key":"ref38","doi-asserted-by":"publisher","DOI":"10.1039\/P29940001509"},{"key":"ref39","doi-asserted-by":"publisher","DOI":"10.1021\/ol902039q"},{"key":"ref40","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2364(74)90275-3"},{"key":"ref41","doi-asserted-by":"publisher","DOI":"10.1021\/ja205602j"}],"container-title":["Beilstein Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/14\/27","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/content\/pdf\/1860-5397-14-27.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/14\/27","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/14\/27","content-type":"text\/html","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,6,24]],"date-time":"2021-06-24T07:43:06Z","timestamp":1624520586000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/14\/27"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,2,12]]},"references-count":41,"URL":"https:\/\/doi.org\/10.3762\/bjoc.14.27","archive":["Portico"],"relation":{},"ISSN":["1860-5397"],"issn-type":[{"value":"1860-5397","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,2,12]]}}}