{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T11:37:58Z","timestamp":1747222678395,"version":"3.40.5"},"reference-count":41,"publisher":"Beilstein Institut","license":[{"start":{"date-parts":[[2019,6,21]],"date-time":"2019-06-21T00:00:00Z","timestamp":1561075200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2019,6,21]],"date-time":"2019-06-21T00:00:00Z","timestamp":1561075200000},"content-version":"am","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2019,6,21]],"date-time":"2019-06-21T00:00:00Z","timestamp":1561075200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Beilstein J. Org. Chem."],"accepted":{"date-parts":[[2019,5,27]]},"abstract":"<jats:p>The quantitative double self-sorting between the three-component rectangle [Cu<jats:sub>4<\/jats:sub>(<jats:bold>1<\/jats:bold>)<jats:sub>2<\/jats:sub>(<jats:bold>2<\/jats:bold>)<jats:sub>2<\/jats:sub>]<jats:sup>4+<\/jats:sup> and the four-component sandwich complex [Cu<jats:sub>2<\/jats:sub>(<jats:bold>1<\/jats:bold>)(<jats:bold>2<\/jats:bold>)(<jats:bold>4<\/jats:bold>)]<jats:sup>2+<\/jats:sup> is triggered by inclusion and release of DABCO (<jats:bold>4<\/jats:bold>). The fully reversible and clean switching between two multicomponent supramolecular architectures can be monitored by fluorescence changes at the zinc porphyrin sites. The structural changes are accompanied by a huge spatial contraction\/expansion of the zinc porphyrin\u2013zinc porphyrin distances that change from 31.2\/38.8 \u00c5 to 6.6 \u00c5 and back. The supramolecular interconversion was used for the highly selective detection of DABCO in a mixture of other similar compounds.<\/jats:p>","DOI":"10.3762\/bjoc.15.137","type":"journal-article","created":{"date-parts":[[2019,6,21]],"date-time":"2019-06-21T05:44:53Z","timestamp":1561095893000},"page":"1371-1378","source":"Crossref","is-referenced-by-count":4,"title":["Selective detection of DABCO using a supramolecular interconversion as fluorescence reporter"],"prefix":"10.3762","volume":"15","author":[{"given":"Indrajit","family":"Paul","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4226-7147","authenticated-orcid":false,"given":"Debabrata","family":"Samanta","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sudhakar","family":"Gaikwad","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8622-2883","authenticated-orcid":false,"given":"Michael","family":"Schmittel","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"2086","published-online":{"date-parts":[[2019,6,21]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","DOI":"10.1039\/b922293f"},{"key":"ref2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200077m"},{"key":"ref3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b05082"},{"key":"ref4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03541"},{"key":"ref5","doi-asserted-by":"publisher","DOI":"10.1039\/c7dt04571a"},{"key":"ref6","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702573"},{"key":"ref7","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02256"},{"key":"ref8","doi-asserted-by":"publisher","DOI":"10.1039\/c6cc03824g"},{"key":"ref9","doi-asserted-by":"publisher","DOI":"10.1039\/c6sc02012g"},{"key":"ref10","doi-asserted-by":"publisher","DOI":"10.1039\/c5cs00301f"},{"key":"ref11","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200453753"},{"key":"ref12","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905947"},{"key":"ref13","doi-asserted-by":"publisher","DOI":"10.1039\/b926154k"},{"key":"ref14","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp44710c"},{"key":"ref15","doi-asserted-by":"publisher","DOI":"10.1021\/ja411011a"},{"key":"ref16","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509108"},{"key":"ref17","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b04437"},{"key":"ref18","doi-asserted-by":"publisher","DOI":"10.1039\/c7cc05235a"},{"key":"ref19","doi-asserted-by":"publisher","DOI":"10.1039\/c8cc01496e"},{"key":"ref20","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b02386"},{"key":"ref21","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02703"},{"key":"ref22","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01182"},{"key":"ref23","doi-asserted-by":"publisher","DOI":"10.1039\/c8ob00944a"},{"key":"ref24","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411985"},{"key":"ref25","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08694"},{"key":"ref26","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc53211a"},{"key":"ref27","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob25098e"},{"key":"ref28","doi-asserted-by":"publisher","DOI":"10.1039\/c4cs00305e"},{"key":"ref29","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04659"},{"key":"ref30","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2201"},{"key":"ref31","doi-asserted-by":"publisher","DOI":"10.1039\/c4dt02996h"},{"key":"ref32","doi-asserted-by":"publisher","DOI":"10.1016\/bs.adioch.2017.11.006"},{"key":"ref33","doi-asserted-by":"publisher","DOI":"10.1021\/ic400328d"},{"key":"ref34","doi-asserted-by":"publisher","DOI":"10.1021\/ic50080a022"},{"key":"ref35","doi-asserted-by":"publisher","DOI":"10.1007\/s10847-015-0584-x"},{"key":"ref36","doi-asserted-by":"publisher","DOI":"10.1021\/jo201252q"},{"key":"ref37","doi-asserted-by":"publisher","DOI":"10.1021\/ja001364u"},{"key":"ref38","doi-asserted-by":"publisher","DOI":"10.1021\/ic001038f"},{"key":"ref39","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002271"},{"key":"ref40","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200400772"},{"key":"ref41","doi-asserted-by":"publisher","DOI":"10.1039\/c8dt00128f"}],"container-title":["Beilstein Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/15\/137","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/content\/pdf\/1860-5397-15-137.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/15\/137","content-type":"text\/html","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,6,24]],"date-time":"2021-06-24T08:19:31Z","timestamp":1624522771000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/15\/137"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,6,21]]},"references-count":41,"URL":"https:\/\/doi.org\/10.3762\/bjoc.15.137","archive":["Portico"],"relation":{},"ISSN":["1860-5397"],"issn-type":[{"type":"electronic","value":"1860-5397"}],"subject":[],"published":{"date-parts":[[2019,6,21]]}}}