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Org. Chem."],"accepted":{"date-parts":[[2022,10,6]]},"abstract":"<jats:p>A triferrocenyl trithiophosphite was studied by X-ray single-crystal diffraction. Triferrocenyl trithiophosphite has nine axes of internal rotation: three P\u2013S bonds, three C\u2013S bonds and three Fe\u2013cyclopentadienyl axes. Rotation around the P\u2013S bonds results in a totally asymmetric structure with three ferrocenylthio groups exhibiting different orientations towards the phosphorus lone electron pair (LEP). 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