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Chem."],"accepted":{"date-parts":[[2023,6,16]]},"abstract":"<jats:p>\n                    Siderophores are small molecules secreted by microorganisms in order to scavenge iron from the environment. An example is the thiazoline-containing natural product massiliachelin, which is produced by\n                    <jats:italic>Massilia<\/jats:italic>\n                    sp. NR 4-1 under iron-deficient conditions. Based on experimental evidence and genome analysis, it was suspected that this bacterium synthesizes further iron-chelating molecules. After a thorough inspection of its metabolic profile, six previously overlooked compounds were isolated that were active in the chrome azurol S (CAS) assay. Mass spectrometric measurements and nuclear magnetic resonance spectroscopic analyses identified these compounds as possible biosynthetic intermediates or shunt products of massiliachelin. Their bioactivity was tested against one Gram-positive and three Gram-negative bacteria.\n                  <\/jats:p>","DOI":"10.3762\/bjoc.19.69","type":"journal-article","created":{"date-parts":[[2023,6,23]],"date-time":"2023-06-23T04:27:09Z","timestamp":1687494429000},"page":"909-917","source":"Crossref","is-referenced-by-count":5,"title":["Intermediates and shunt products of massiliachelin biosynthesis in\n                    <i>Massilia<\/i>\n                    sp. 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