{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T14:43:09Z","timestamp":1785422589369,"version":"3.56.0"},"reference-count":32,"publisher":"Beilstein Institut","license":[{"start":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T00:00:00Z","timestamp":1722211200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T00:00:00Z","timestamp":1722211200000},"content-version":"am","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T00:00:00Z","timestamp":1722211200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Beilstein J. Org. Chem."],"accepted":{"date-parts":[[2024,7,3]]},"abstract":"<jats:p>\n                    The ability to investigate hypervalent iodine(V) fluorides has been limited primarily by their difficult preparation traditionally using harsh fluorinating reagents such as trifluoromethyl hypofluorite and bromine trifluoride. Here, we report a mild and efficient route using Selectfluor to deliver hypervalent iodine(V) fluorides in good isolated yields (72\u201390%). Stability studies revealed that bicyclic difluoro(aryl)-\u03bb\n                    <jats:sup>5<\/jats:sup>\n                    -iodane\n                    <jats:bold>6<\/jats:bold>\n                    was much more stable in acetonitrile-\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    than in chloroform-\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>1<\/jats:sub>\n                    , presumably due to acetonitrile coordinating to the iodine(V) centre and stabilising it via halogen bonding.\n                  <\/jats:p>","DOI":"10.3762\/bjoc.20.157","type":"journal-article","created":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T07:57:01Z","timestamp":1722239821000},"page":"1785-1793","source":"Crossref","is-referenced-by-count":1,"title":["Oxidative fluorination with Selectfluor: A convenient procedure for preparing hypervalent iodine(V) 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