{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T23:37:17Z","timestamp":1790293037531,"version":"4.1.0"},"reference-count":30,"publisher":"Beilstein Institut","license":[{"start":{"date-parts":[[2024,1,30]],"date-time":"2024-01-30T00:00:00Z","timestamp":1706572800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2024,1,30]],"date-time":"2024-01-30T00:00:00Z","timestamp":1706572800000},"content-version":"am","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2024,1,30]],"date-time":"2024-01-30T00:00:00Z","timestamp":1706572800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/501100001602","name":"Science Foundation Ireland","doi-asserted-by":"publisher","award":["Awards 13\/IA\/1959 and 20\/FFP-P\/884"],"award-info":[{"award-number":["Awards 13\/IA\/1959 and 20\/FFP-P\/884"]}],"id":[{"id":"10.13039\/501100001602","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004543","name":"China Scholarship Council","doi-asserted-by":"publisher","award":["PhD scholarship"],"award-info":[{"award-number":["PhD scholarship"]}],"id":[{"id":"10.13039\/501100004543","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Beilstein J. Org. Chem."],"accepted":{"date-parts":[[2024,1,16]]},"abstract":"<jats:p>\n                    The synthesis of gram quantities of the TF antigen (\u03b2-\u1d05-Gal-(1\u21923)-\u03b1-\u1d05-GalNAc) and its 3\u2019-sulfated analogue with a TEG-N\n                    <jats:sub>3<\/jats:sub>\n                    spacer attached is described. The synthesis of the TF antigen comprises seven steps, from a known\n                    <jats:italic>N<\/jats:italic>\n                    -Troc-protected galactosamine donor, with an overall yield of 31%. Both the spacer (85%) and the galactose moiety (79%) were introduced using thioglycoside donors in NIS\/AgOTf-promoted glycosylation reactions. The 3\u2019-sulfate was finally introduced through tin activation in benzene\/DMF followed by treatment with a sulfur trioxide\u2013trimethylamine complex in a 66% yield.\n                  <\/jats:p>","DOI":"10.3762\/bjoc.20.17","type":"journal-article","created":{"date-parts":[[2024,1,30]],"date-time":"2024-01-30T08:48:28Z","timestamp":1706604508000},"page":"173-180","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis of the 3\u2019-\n                    <i>O<\/i>\n                    -sulfated TF antigen with a TEG-N\n                    <sub>3<\/sub>\n                    linker for glycodendrimersomes preparation to study lectin 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