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Org. Chem."],"accepted":{"date-parts":[[2025,12,10]]},"abstract":"<jats:p>Alkenyl chlorides constitute a synthetically valuable yet historically underexplored class of organohalides. First prepared in 1868 by Charles Friedel \u2013 best known for the Friedel\u2013Crafts reaction \u2013 via the reaction of ketones with phosphorus pentachloride, these compounds have steadily gained attention over the decades. In recent years, their distinct reactivity and potential in organic synthesis have been increasingly recognized. This review provides a comprehensive overview of the synthesis and application of alkenyl chlorides, with a focus on developments over the past four decades. 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