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Org. Chem."],"accepted":{"date-parts":[[2026,9,15]]},"abstract":"<jats:p>\n                    Divalent samarium reagents, particularly samarium diiodide (SmI\n                    <jats:sub>2<\/jats:sub>\n                    ), have long been recognized as the most powerful and versatile single-electron reductants in organic synthesis. Several catalytic strategies have been developed for Sm(II) chemistry over the past three decades, including approaches based on metal co-reductants, electrochemical reduction, and radical relay mechanisms. Photochemical strategies have recently emerged as new platforms for catalytic Sm(II) chemistry, leading to the development of a broad range of reductive transformations. 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