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Chem."],"accepted":{"date-parts":[[2013,11,4]]},"abstract":"<jats:p>Oxidative cyclization of 6-chloro-4-pyrimidinylhydrazones <jats:bold>4<\/jats:bold> with iodobenzene diacetate (IBD) in dichloromethane gives rise to [1,2,4]triazolo[4,3-<jats:italic>c<\/jats:italic>]pyrimidine derivatives <jats:bold>5a<\/jats:bold>\u2013<jats:bold>o<\/jats:bold>. These incipient products undergo feasible Dimroth rearrangement to furnish the isolated [1,2,4]triazolo[1,5-<jats:italic>c<\/jats:italic>]pyrimidines <jats:bold>6a<\/jats:bold>\u2013<jats:bold>o<\/jats:bold> in moderate to high yields.<\/jats:p>","DOI":"10.3762\/bjoc.9.298","type":"journal-article","created":{"date-parts":[[2013,11,25]],"date-time":"2013-11-25T08:57:14Z","timestamp":1385369834000},"page":"2629-2634","source":"Crossref","is-referenced-by-count":14,"title":["IBD-mediated oxidative cyclization of pyrimidinylhydrazones and concurrent Dimroth rearrangement: Synthesis of [1,2,4]triazolo[1,5-<i>c<\/i>]pyrimidine derivatives"],"prefix":"10.3762","volume":"9","author":[{"given":"Caifei","family":"Tang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiming","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quanrui","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"2086","published-online":{"date-parts":[[2013,11,25]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","DOI":"10.1002\/cbdv.200490173"},{"key":"ref2","volume-title":"Progress in Heterocyclic Chemistry","volume":"18","author":"Gribble","year":"2007"},{"key":"ref4","doi-asserted-by":"publisher","DOI":"10.1021\/ol900350k"},{"key":"ref5","doi-asserted-by":"publisher","DOI":"10.1097\/00005344-200001000-00001"},{"key":"ref6","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejphar.2005.04.013"},{"key":"ref7","doi-asserted-by":"publisher","DOI":"10.1021\/np100298m"},{"key":"ref8","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2011.11.037"},{"key":"ref9","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2009.10.007"},{"key":"ref10","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-2725(08)60942-3"},{"key":"ref11","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-2725(00)77009-7"},{"key":"ref12","doi-asserted-by":"publisher","DOI":"10.1002\/hc.20114"},{"key":"ref13","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2008.11.075"},{"key":"ref14","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001999"},{"key":"ref15","doi-asserted-by":"publisher","DOI":"10.1055\/s-0030-1258514"},{"key":"ref16","doi-asserted-by":"publisher","DOI":"10.1039\/b305458f"},{"key":"ref17","first-page":"61","volume":"52","author":"Biagi","year":"1997","journal-title":"Il Farmaco"},{"key":"ref18","doi-asserted-by":"publisher","DOI":"10.1021\/cr800332c"},{"key":"ref19","doi-asserted-by":"publisher","DOI":"10.1021\/jo1024738"},{"key":"ref20","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2010.11.054"},{"key":"ref21","doi-asserted-by":"publisher","DOI":"10.1002\/9781118092828.ch9"},{"key":"ref23","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.9.212"}],"container-title":["Beilstein Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/9\/298","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/content\/pdf\/1860-5397-9-298.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/www.beilstein-journals.org\/bjoc\/content\/9\/1\/298","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/9\/298","content-type":"text\/html","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,6,22]],"date-time":"2021-06-22T12:04:52Z","timestamp":1624363492000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.beilstein-journals.org\/bjoc\/articles\/9\/298"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,11,25]]},"references-count":21,"URL":"https:\/\/doi.org\/10.3762\/bjoc.9.298","archive":["Portico"],"relation":{},"ISSN":["1860-5397"],"issn-type":[{"value":"1860-5397","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,11,25]]}}}