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Inorganic Chemistry. 34, 3339-3348, doi:10.1021\/ic00116a028 (1995).","journal-title":"Inorganic Chemistry"},{"key":"ref6","doi-asserted-by":"crossref","first-page":"315","DOI":"10.1016\/0022-0728(86)87080-2","type":"journal-article","article-title":"Electrochemical coating of a platinum electrode by a poly(pyrrole) film containing the fac-Re(2,2'-bipyridine)(CO)3Cl system application to electrocatalytic reduction of CO2","volume":"207","author":"Cosnier","year":"1986","unstructured":"Cosnier, S., Deronzier, A., & Moutet, J.-C. Electrochemical coating of a platinum electrode by a poly(pyrrole) film containing the fac-Re(2,2'-bipyridine)(CO)3Cl system application to electrocatalytic reduction of CO2. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 207, 315-321, doi:10.1016\/0022-0728(86)87080-2 (1986).","journal-title":"Journal of Electroanalytical Chemistry and Interfacial Electrochemistry"},{"key":"ref7","doi-asserted-by":"crossref","first-page":"381","DOI":"10.1016\/0304-5102(88)80070-1","type":"journal-article","article-title":"Electrocatalytic reduction of CO2 on electrodes modified by fac-Re(2,2'-bipyridine)(CO)3Cl complexes bonded to polypyrrole films","volume":"45","author":"Cosnier","year":"1988","unstructured":"Cosnier, S., Deronzier, A., & Moutet, J.-C. Electrocatalytic reduction of CO2 on electrodes modified by fac-Re(2,2'-bipyridine)(CO)3Cl complexes bonded to polypyrrole films. Journal of Molecular Catalysis. 45, 381-391, doi:10.1016\/0304-5102(88)80070-1 (1988).","journal-title":"Journal of Molecular Catalysis"},{"key":"ref8","doi-asserted-by":"crossref","first-page":"1416","DOI":"10.1039\/c39850001416","type":"journal-article","article-title":"Electrocatalytic reduction of CO2 at a chemically modified electrode","volume":"20","author":"Toole","year":"1985","unstructured":"Toole, T. R., et al. Electrocatalytic reduction of CO2 at a chemically modified electrode. Journal of the Chemical Society, Chemical Communications. 20, 1416-1417 (1985).","journal-title":"Journal of the Chemical Society, Chemical Communications"},{"key":"ref9","first-page":"6468","type":"journal-article","article-title":"Ruthenium Terpyridine Complexes Containing a Pyrrole-Tagged 2,2\u2032-Dipyridylamine Ligand\u2014Synthesis","volume":"51","author":"Cheung","year":"2012","unstructured":"Cheung, K.-C., et al. 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Journal of the American Chemical Society. 136, 6578-6581, doi:10.1021\/ja502464s (2014).","journal-title":"Journal of the American Chemical Society"},{"key":"ref11","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1021\/ja00391a001","type":"journal-article","article-title":"Rectifying interfaces using two-layer films of electrochemically polymerized vinylpyridine and vinylbipyridine complexes of ruthenium and iron on electrodes","volume":"103","author":"Abru\u00f1a","year":"1981","unstructured":"Abru\u00f1a, H. D., Denisevich, P., Umana, M., Meyer, T. J., & Murray, R. W. Rectifying interfaces using two-layer films of electrochemically polymerized vinylpyridine and vinylbipyridine complexes of ruthenium and iron on electrodes. Journal of the American Chemical Society. 103, 1-5, doi:10.1021\/ja00391a001 (1981).","journal-title":"Journal of the American Chemical Society"},{"key":"ref12","doi-asserted-by":"crossref","first-page":"5521","DOI":"10.1021\/ic00052a030","type":"journal-article","article-title":"Microstructures in thin polymeric films. Photochemically produced molecular voids","volume":"31","author":"Gould","year":"1992","unstructured":"Gould, S., Gray, K. H., Linton, R. W., & Meyer, T. J. Microstructures in thin polymeric films. Photochemically produced molecular voids. Inorganic Chemistry. 31, 5521-5525, doi:10.1021\/ic00052a030 (1992).","journal-title":"Inorganic Chemistry"},{"key":"ref13","doi-asserted-by":"crossref","first-page":"4535","DOI":"10.1021\/jp971076t","type":"journal-article","article-title":"Excited State Interactions in Electropolymerized Thin Films of Ru(II)","volume":"101","author":"Devenney","year":"1997","unstructured":"Devenney, M. et al. 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Journal of the American Chemical Society. 133, 20720-20723, doi:10.1021\/ja209620p (2011).","journal-title":"Journal of the American Chemical Society"},{"key":"ref18","doi-asserted-by":"crossref","first-page":"4747","DOI":"10.1021\/ic302472r","type":"journal-article","article-title":"Coordination Chemistry of Single-Site Catalyst Precursors in Reductively Electropolymerized Vinylbipyridine Films","volume":"52","author":"Harrison","year":"2013","unstructured":"Harrison, D. P., et al. Coordination Chemistry of Single-Site Catalyst Precursors in Reductively Electropolymerized Vinylbipyridine Films. 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Angewandte Chemie International Edition. 47, 5830-5832, doi:10.1002\/anie.200704912 (2008).","journal-title":"Angewandte Chemie International Edition"},{"key":"ref23","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1016\/0010-8545(95)01130-7","type":"journal-article","article-title":"Polypyrrole films containing metal complexes: syntheses and applications","volume":"147","author":"Deronzier","year":"1996","unstructured":"Deronzier, A., & Moutet, J.-C. Polypyrrole films containing metal complexes: syntheses and applications. Coordination Chemistry Reviews. 147, 339-371, doi:http:\/\/dx.doi.org\/10.1016\/0010-8545(95)01130-7 (1996).","journal-title":"Coordination Chemistry Reviews"},{"key":"ref24","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1039\/a807124a","type":"journal-article","article-title":"The mechanisms of pyrrole electropolymerization","volume":"29","author":"Sabouraud","year":"2000","unstructured":"Sabouraud, G., Sadki, S., & Brodie, N. 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Inorganic Chemistry. 21, 2153-2161, doi:10.1021\/ic00136a006 (1982).","journal-title":"Inorganic Chemistry"},{"key":"ref26","doi-asserted-by":"crossref","first-page":"3280","DOI":"10.1021\/ic00041a022","type":"journal-article","article-title":"Electrocatalytic reduction of nitrite and nitrosyl by iron(III) protoporphyrin IX dimethyl ester immobilized in an electropolymerized film","volume":"31","author":"Younathan","year":"1992","unstructured":"Younathan, J. N., Wood, K. S., & Meyer, T. J. Electrocatalytic reduction of nitrite and nitrosyl by iron(III) protoporphyrin IX dimethyl ester immobilized in an electropolymerized film. Inorganic Chemistry. 31, 3280-3285, doi:10.1021\/ic00041a022 (1992).","journal-title":"Inorganic Chemistry"},{"key":"ref27","doi-asserted-by":"crossref","first-page":"2683","DOI":"10.1021\/ja00374a001","type":"journal-article","article-title":"Permeation of electroactive solutes through ultrathin polymeric films on electrode surfaces","volume":"104","author":"Ikeda","year":"1982","unstructured":"Ikeda, T., Schmehl, R., Denisevich, P., Willman, K., & Murray, R. W. Permeation of electroactive solutes through ultrathin polymeric films on electrode surfaces. Journal of the American Chemical Society. 104, 2683-2691, doi:10.1021\/ja00374a001 (1982).","journal-title":"Journal of the American Chemical Society"},{"key":"ref28","doi-asserted-by":"crossref","first-page":"1954","DOI":"10.1021\/ar9001526","type":"journal-article","article-title":"Making Oxygen with Ruthenium Complexes","volume":"42","author":"Concepcion","year":"2009","unstructured":"Concepcion, J. J., et al. 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Journal of the American Chemical Society. 131, 15580-15581, doi:10.1021\/ja906391w (2009).","journal-title":"Journal of the American Chemical Society"},{"key":"ref30","doi-asserted-by":"crossref","first-page":"15450","DOI":"10.1021\/ja4055977","type":"journal-article","article-title":"Stabilization of a Ruthenium(II) Polypyridyl Dye on Nanocrystalline TiO2 by an Electropolymerized Overlayer","volume":"135","author":"Lapides","year":"2013","unstructured":"Lapides, A. M. et al. Stabilization of a Ruthenium(II) Polypyridyl Dye on Nanocrystalline TiO2 by an Electropolymerized Overlayer. Journal of the American Chemical Society. 135, 15450-15458, doi:10.1021\/ja4055977 (2013).","journal-title":"Journal of the American Chemical Society"},{"key":"ref31","doi-asserted-by":"crossref","first-page":"8718","DOI":"10.1021\/jp011281f","type":"journal-article","article-title":"Electrochemical and Spectroelectrochemical Investigations into the Nature of Charge-Trapping in Electrochemically-Generated Homopolymer Films of Tris(4-vinyl-4\u2018-methyl-2,2\u2018-bipyridine)ruthenium(II)","volume":"105","author":"Paulson","year":"2001","unstructured":"Paulson, S. C., Sapp, S. A., & Elliott, C. M. Electrochemical and Spectroelectrochemical Investigations into the Nature of Charge-Trapping in Electrochemically-Generated Homopolymer Films of Tris(4-vinyl-4\u2018-methyl-2,2\u2018-bipyridine)ruthenium(II)\u2020. The Journal of Physical Chemistry B. 105, 8718-8724, doi:10.1021\/jp011281f (2001).","journal-title":"The Journal of Physical Chemistry B"},{"key":"ref32","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1016\/S0022-0728(80)80496-7","type":"journal-article","article-title":"General expression of the linear potential sweep voltammogram for a surface redox reaction with interactions between the adsorbed molecules: Applications to modified electrodes","volume":"115","author":"Laviron","year":"1980","unstructured":"Laviron, E., & Roullier, L. General expression of the linear potential sweep voltammogram for a surface redox reaction with interactions between the adsorbed molecules: Applications to modified electrodes J. Electroanal. Chem. Interfacial Electrochem. 115, 65-74 (1980).","journal-title":"J. Electroanal. Chem. 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Electrodeposited, \u201cTextured\u201d Poly(3-hexyl-thiophene) (e-P3HT) Films for Photovoltaic Applications. Chemistry of Materials. 20, 5796-5806, doi:10.1021\/cm8008122 (2008).","journal-title":"Chemistry of Materials"}],"container-title":["Journal of Visualized Experiments"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/www.jove.com\/video\/52035\/reductive-electropolymerization-vinyl-containing-poly-pyridyl-complex","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T16:39:58Z","timestamp":1792687198000},"score":1,"resource":{"primary":{"URL":"https:\/\/app.jove.com\/t\/52035"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,1,30]]},"references-count":34,"journal-issue":{"issue":"95","published-online":{"date-parts":[[2015]]}},"URL":"https:\/\/doi.org\/10.3791\/52035","relation":{},"ISSN":["1940-087X"],"issn-type":[{"value":"1940-087X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,1,30]]}}}