{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T13:33:54Z","timestamp":1760708034677},"reference-count":20,"publisher":"CLOCKSS Archive","issue":"7","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["HETEROCYCLES"],"published-print":{"date-parts":[[2000]]},"DOI":"10.3987\/com-00-8920","type":"journal-article","created":{"date-parts":[[2009,3,3]],"date-time":"2009-03-03T01:49:28Z","timestamp":1236044968000},"page":"1485","source":"Crossref","is-referenced-by-count":28,"title":["Palladium-catalyzed Asymmetric Allylic Alkylation Using Chiral P,N-Ligands"],"prefix":"10.13030","volume":"53","author":[{"given":"Takashi","family":"Mino","sequence":"first","affiliation":[]},{"given":"Youichi","family":"Tanaka","sequence":"additional","affiliation":[]},{"given":"Masami","family":"Sakamoto","sequence":"additional","affiliation":[]},{"given":"Tsutomu","family":"Fujita","sequence":"additional","affiliation":[]}],"member":"5187","reference":[{"key":"#cr-split#-10.3987\/COM-00-8920-1.1","doi-asserted-by":"crossref","unstructured":"(a) J. 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Ikeda, Tetrahedron: Asymmetry, 1998, 9, 3371. (d) J. P. Cahill, and P. J. Guiry, Tetrahedron: Asymmetry, 1998, 9, 4301. (e) Y. Imai, W. Zhang, T. Kida, Y. Nakatsuji, and I. Ikeda, Tetrahedron Lett., 1998, 39, 4343. (f) B. Wiese and G. Helmchem, Tetrahedron Lett., 1998, 39, 5727. (g) K. Yonehara, T. Hashizume, K. Mori, K. Ohe, and S. Uemura, Chem. Commun., 1998, 415. (h) A. Saitoh, M. Misawa, and T. Morimoto, Synlett, 1999, 483. (i) Y. Suzuki, Y. Ogata, and K. Hiroi, Tetrahedron: Asymmetry, 1999, 10, 1219. (j) J. C. Anderson, R. J. Cubbon, and J. D. Harling, Tetrahedron: Asymmetry, 1999, 10, 2829. (k) J. W. Han, H-Y. Jang, and Y. K. Chung, Tetrahedron: Asymmetry, 1999, 10, 2853. (l) K. Ito, R. Kashiwagi, K. Iwasaki, and T. Katsuki, Synlett, 1999, 1563.","DOI":"10.1016\/S0957-4166(98)00073-1"},{"key":"10.3987\/COM-00-8920-4","doi-asserted-by":"crossref","unstructured":"4. P. Wimmer and M. 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Brown, Tetrahedron: Asymmetry, 1995, 6, 2597.","DOI":"10.1016\/0957-4166(95)00341-L"},{"key":"10.3987\/COM-00-8920-10","unstructured":"10. 5a: [\u03b1] D20 = +8.2\u00b0 (c=1.00, CHCl3); 1H NMR (300 Mz, CDCl3) \u03b4 1.54-1.86 (m, 3H), 2.01-2.16 (m, 1H), 2.63 (t, 8.9 Hz, 1H), 2.72 (q, 7.1 Hz, 1H), 3.03 (dd, 3.7 and 9.2 Hz, 1H), 3.12 (s, 3H), 3.45-3.56 (m, 1H), 3.63-3.77 (m, 1H), 6.81 (dq, 1.3 and 3.8 Hz, 1H), 6.94 (t, 7.4 Hz, 1H), 7.18-7.39 (m, 12H); 31P NMR (121 Mz, CDCl3) \u03b4 -12.14; FAB-MS m \/ z 376 (M++H, 64).; 5b: [\u03b1] D20 = -12.3\u00b0 (c=1.00, CHCl3); 1H NMR (300 Mz, CDCl3) \u03b4 2.00 (br, 3H), 2.39 (br, 1H), 2.89 (br, 1H), 3.09 (s, 3H), 3.22 (br, 3H), 4.08 (br, 1H), 7.06 (br, 1H), 7.14-7.38 (m, 11H), 7.47 (br, 2H), 7.60 (d, 8.5 Hz, 1H), 7.85 (br, 1H); 31P NMR (121 Mz, CDCl3) \u03b4 -16.22; FAB-MS m \/ z 426 (M++H, 57).; 5c: [\u03b1] D20 = -31.0\u00b0 (c=1.00, CHCl3); 1H NMR (300 Mz, CDCl3) \u03b4 1.57-1.91 (m, 3H), 2.02-2.20 (m, 1H), 2.43 (t, 8.9 Hz, 1H), 2.75 (q, 7.7 Hz, 1H), 2.97 (dd, 3.7 and 9.2 Hz, 1H), 3.08 (s, 3H), 3.70-3.88 (m, 2H), 6.95-7.18 (m, 2H), 7.22-7.43 (m, 11H), 7.53 (d, 8.4 Hz, 1H), 7.56 (d, 4.5 Hz, 1H), 7.70 (d, 8.1 Hz, 1H); 31P NMR (121 Mz, CDCl3) \u03b4 -10.46.; 5d: [\u03b1] D20 = 32.0\u00b0 (c=1.00, CHCl3); 1H NMR (300 Mz, CDCl3) \u03b4 1.60-1.81 (m, 3H), 2.01-2.19 (m, 1H), 2.92-3.02 (m, 1H), 3.11 (s, 3H), 3.15 (dd, 7.2 and 9.3 Hz, 1H), 3.34 (dd, 4.3 and 9.3 Hz, 1H), 3.66-3.78 (m, 1H), 3.98-4.11 (m, 1H), 6.80-6.87 (m, 1H), 6.96-7.17 (m, 6H), 7.19-7.28 (m, 3H), 7.38-7.49 (m, 4H), 7.61 (d, 7.9 Hz, 1H), 7.76 (d, 9.0 Hz, 1H) ; 31P NMR (121 Mz, CDCl3) \u03b4 -16.05."},{"key":"10.3987\/COM-00-8920-11","unstructured":"11. The enantiomer of 5b was previously synthesized: S. Miyano, T. Hattori, Y. Komuro, H. Kumobayashi, Jpn. Kokai Tokkyo Koho, H09241277 (Chem. Abstr., 1997, 127, 302486h)."},{"key":"10.3987\/COM-00-8920-12","doi-asserted-by":"crossref","unstructured":"12. T. Hayashi, A. Yamamoto, T. Hagihara, and Y. 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