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Crystal data (excluding structure factors) deposited at the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 684401: C16H25NO3S, M = 311.43; monoclinic, a = 12.375(2) \u00c5, b = 5.7906(10) \u00c5, c = 12.893(2) \u00c5, \u03b2 = 115.430(3); V = 834.4(2) \u00c53; space group P2(1); Z = 2; Dc = 1.240 Mg m-3; \u03bb = 0.71073 \u00c5; \u03bc = 0.203 mm-1; F(000) = 336; T = 21\u00b11 \u00b0C. Data collection was performed on a Bruker Smart CCD diffractometer, based on three \u03c9-scan runs (starting = -34\u00b0) at values \u03c6 =0\u00b0, 120\u00b0, 240\u00b0 with the detector at 2\u03b8 =-32\u00b0. For each of these runs, 606 frames were collected at 0.3\u00b0 intervals and 10 s per frame. An additional run at \u03c6 =0\u00b0 of 100 frames was collected to improve redundancy. The diffraction frames were integrated using the program SAINT and the integrated intensities were corrected for Lorentz-polarization effects with SADABS. 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