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Model Dev."],"abstract":"<jats:p>\n                    The Goddard Earth Observing System with chemistry (GEOS-Chem) model has been\nupdated with the State-wide Air Pollution Research Center version\u00a011\u00a0(SAPRC-11) aromatics chemical\nmechanism, with the purpose of evaluating global and regional effects of the\nmost abundant aromatics (benzene, toluene, xylenes) on the chemical species\nimportant for tropospheric oxidation capacity. The model evaluation based on\nsurface and aircraft observations indicates good agreement for aromatics and\nozone. A comparison between scenarios in GEOS-Chem with simplified aromatic\nchemistry (as in the standard setup, with no ozone formation from related\nperoxy radicals or recycling of NO\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    ) and with the SAPRC-11 scheme\nreveals relatively slight changes in ozone, the hydroxyl radical, and nitrogen\noxides on a global mean basis (1\u2009%\u20134\u2009%), although remarkable regional\ndifferences (5\u2009%\u201320\u2009%) exist near the source regions. NO\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    decreases\nover the source regions and increases in the remote troposphere, due mainly\nto more efficient transport of peroxyacetyl nitrate\u00a0(PAN), which is\nincreased with the SAPRC aromatic chemistry. Model ozone mixing ratios with\nthe updated aromatic chemistry increase by up to 5\u2009ppb (more than 10\u2009%),\nespecially in industrially polluted regions. The ozone change is partly due\nto the direct influence of aromatic oxidation products on ozone production\nrates, and in part to the altered spatial distribution of NO\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    that\nenhances the tropospheric ozone production efficiency. Improved\nrepresentation of aromatics is important to simulate the tropospheric oxidation.\n                  <\/jats:p>","DOI":"10.5194\/gmd-12-111-2019","type":"journal-article","created":{"date-parts":[[2019,1,4]],"date-time":"2019-01-04T05:17:44Z","timestamp":1546579064000},"page":"111-130","source":"Crossref","is-referenced-by-count":25,"title":["Global tropospheric effects of aromatic chemistry with the SAPRC-11 mechanism implemented in GEOS-Chem version\u00a09-02"],"prefix":"10.5194","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6251-0899","authenticated-orcid":false,"given":"Yingying","family":"Yan","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"Cabrera-Perez","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2362-2940","authenticated-orcid":false,"given":"Jintai","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"},{"role":"corresponding-author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2440-6104","authenticated-orcid":false,"given":"Andrea","family":"Pozzer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3076-125X","authenticated-orcid":false,"given":"Dylan B.","family":"Millet","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3121-8323","authenticated-orcid":false,"given":"William C.","family":"Porter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6307-3846","authenticated-orcid":false,"given":"Jos","family":"Lelieveld","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"3145","published-online":{"date-parts":[[2019,1,4]]},"reference":[{"key":"ref1","doi-asserted-by":"publisher","unstructured":"Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmos. 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