{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,21]],"date-time":"2025-10-21T15:05:57Z","timestamp":1761059157168,"version":"3.41.0"},"reference-count":0,"publisher":"Rubber Division, ACS","issue":"5","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2009,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n        <jats:p>Physical blends and thermoplastic vulcanizates (TPVs) based on EPDM and PP were prepared in a batch mixer. Dynamic vulcanization of TPVs using resol\/SnCl<jats:sub>2<\/jats:sub> was studied as a function of time. Static and dynamic vulcanization of EPDM in the absence of PP were also studied. Crosslinking of EPDM in the absence of PP is more efficient via static than dynamic vulcanization. For EPDM\/PP-based TPVs the extent of crosslinking reaction versus time decreases as the amount of EPDM increases. Degradation of the EPDM network occurs during dynamic vulcanization, due to the combined action of shearing and high temperature, and increases as EPDM becomes more and more the continuous phase.<\/jats:p>","DOI":"10.5254\/1.3548260","type":"journal-article","created":{"date-parts":[[2011,2,7]],"date-time":"2011-02-07T17:46:07Z","timestamp":1297100767000},"page":"492-505","source":"Crossref","is-referenced-by-count":17,"title":["Degradation of the Rubber Network during Dynamic Vulcanization of EPDM\/PP Blends Using Phenolic Resol"],"prefix":"10.5254","volume":"82","author":[{"given":"C. F.","family":"Antunes","sequence":"first","affiliation":[{"name":"1IPC -Institute for Polymers and Composites, Department of Polymer Engineering, University of Minho 4800-058 Guimares, Portugal; email: cfm@dep.uminho.pt"}]},{"given":"A. V.","family":"Machado","sequence":"additional","affiliation":[{"name":"1IPC -Institute for Polymers and Composites, Department of Polymer Engineering, University of Minho 4800-058 Guimares, Portugal; email: cfm@dep.uminho.pt"}]},{"given":"M.","family":"van Duin","sequence":"additional","affiliation":[{"name":"2DSM Research, P.O. Box 18, 6160 MD Geleen, The Netherlands"}]}],"member":"3223","container-title":["Rubber Chemistry and Technology"],"original-title":[],"link":[{"URL":"https:\/\/rct.kglmeridian.com\/view\/journals\/rcat\/82\/5\/article-p492.xml","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/meridian.allenpress.com\/rct\/article-pdf\/82\/5\/492\/1950043\/1_3548260.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/rct.kglmeridian.com\/downloadpdf\/journals\/rcat\/82\/5\/article-p492.xml","content-type":"text\/html","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/rct.kglmeridian.com\/downloadpdf\/journals\/rcat\/82\/5\/article-p492.xml","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T00:52:48Z","timestamp":1750899168000},"score":1,"resource":{"primary":{"URL":"https:\/\/rct.kglmeridian.com\/view\/journals\/rcat\/82\/5\/article-p492.xml"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,11]]},"references-count":0,"journal-issue":{"issue":"5"},"URL":"https:\/\/doi.org\/10.5254\/1.3548260","relation":{},"ISSN":["1943-4804","0035-9475"],"issn-type":[{"type":"electronic","value":"1943-4804"},{"type":"print","value":"0035-9475"}],"subject":[],"published":{"date-parts":[[2009,11]]}}}