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The anion [Ge<jats:sub>4<\/jats:sub>Se<jats:sub>10<\/jats:sub>]<jats:sup>4<\/jats:sup> in Cs<jats:sub>4<\/jats:sub>Ge<jats:sub>4<\/jats:sub>Se<jats:sub>10<\/jats:sub>)\u00b72 CH<jats:sub>3<\/jats:sub>OH displays an adamantane-like structure in which four GeSe<jats:sub>4<\/jats:sub> tetrahedra are linked via joint vertices. In con\u00adtrast Cs<jats:sub>4<\/jats:sub>Ge<jats:sub>2<\/jats:sub>Se<jats:sub>8<\/jats:sub> contains the novel dinuclear anion [Ge<jats:sub>2<\/jats:sub>Se<jats:sub>8<\/jats:sub>]<jats:sup>4-<\/jats:sup>, the first example of a selenidogermanate(IV) exhibiting Se<jats:sub>2<\/jats:sub> bridging units. Two GeSe<jats:sub>4<\/jats:sub> tetrahedra are linked in this anion through Se-Se bonds to yield a six-membered ring, which displays a chair conformation and crystallographic C<jats:sub>2h<\/jats:sub> symmetry. <\/jats:p>","DOI":"10.1515\/znb-1994-0515","type":"journal-article","created":{"date-parts":[[2015,2,17]],"date-time":"2015-02-17T17:11:24Z","timestamp":1424193084000},"page":"655-659","source":"Crossref","is-referenced-by-count":29,"title":["Darstellung und Kristallstruktur der C\u00e4sium-Selenidogermanate(IV) Cs<sub>4<\/sub>Ge<sub>4<\/sub>Se<sub>10<\/sub> \u00b7 2CH<sub>3<\/sub>OH und Cs<sub>4<\/sub>Ge<sub>2<\/sub>Se<sub>8<\/sub> \/ Preparation and Crystal Structure of the Cesium Selenidogerm anates(IV) Cs<sub>4<\/sub>Ge<sub>4<\/sub>Se<sub>10<\/sub> \u00b7 2CH<sub>3<\/sub>OH and Cs<sub>4<\/sub>Ge<sub>2<\/sub>Se<sub>8<\/sub>"],"prefix":"10.1515","volume":"49","author":[{"given":"W. S.","family":"Sheldrick","sequence":"first","affiliation":[{"name":"Lehrstuhl f\u00fcr Analytische Chemie der Ruhr-Universit\u00e4t Bochum, D-44780 Bochum"}]},{"given":"B.","family":"Schaaf","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Analytische Chemie der Ruhr-Universit\u00e4t Bochum, D-44780 Bochum"}]}],"member":"374","published-online":{"date-parts":[[2014,6,2]]},"container-title":["Zeitschrift f\u00fcr Naturforschung B"],"language":"en","link":[{"URL":"https:\/\/www.degruyter.com\/view\/journals\/znb\/49\/5\/article-p655.xml","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1994-0515\/xml","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1994-0515\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,6,22]],"date-time":"2021-06-22T16:43:57Z","timestamp":1624380237000},"score":16.079782,"resource":{"primary":{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1994-0515\/html"}},"issued":{"date-parts":[[1994,5,1]]},"references-count":0,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2014,6,2]]},"published-print":{"date-parts":[[1994,5,1]]}},"alternative-id":["10.1515\/znb-1994-0515"],"URL":"https:\/\/doi.org\/10.1515\/znb-1994-0515","ISSN":["1865-7117","0932-0776"],"issn-type":[{"value":"1865-7117","type":"electronic"},{"value":"0932-0776","type":"print"}],"published":{"date-parts":[[1994,5,1]]}},{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T09:21:05Z","timestamp":1753867265893,"version":"3.41.2"},"reference-count":1,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2004,1,9]],"date-time":"2004-01-09T00:00:00Z","timestamp":1073606400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ChemInform"],"published-print":{"date-parts":[[2004,2,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>For Abstract see ChemInform Abstract in Full Text.<\/jats:p>","DOI":"10.1002\/chin.200405004","type":"journal-article","created":{"date-parts":[[2005,7,28]],"date-time":"2005-07-28T22:54:34Z","timestamp":1122591274000},"source":"Crossref","is-referenced-by-count":0,"title":["Cs[Si<sub>3<\/sub>O<sub>6<\/sub>(OH)] and Rb[Si<sub>2<\/sub>O<sub>4<\/sub>(OH)]: Two Novel Phyllosilicates."],"prefix":"10.1002","volume":"35","author":[{"given":"Ivor","family":"Bull","sequence":"first","affiliation":[]},{"given":"John B.","family":"Parise","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2004,1,9]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270103014586"}],"container-title":["ChemInform"],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchin.200405004","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chin.200405004","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,18]],"date-time":"2023-10-18T15:15:25Z","timestamp":1697642125000},"score":15.664274,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/chin.200405004"}},"issued":{"date-parts":[[2004,1,9]]},"references-count":1,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2004,2,3]]}},"alternative-id":["10.1002\/chin.200405004"],"URL":"https:\/\/doi.org\/10.1002\/chin.200405004","archive":["Portico"],"ISSN":["0931-7597","1522-2667"],"issn-type":[{"type":"print","value":"0931-7597"},{"type":"electronic","value":"1522-2667"}],"published":{"date-parts":[[2004,1,9]]},"article-number":"chin.200405004"},{"indexed":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T07:15:19Z","timestamp":1773818119591,"version":"3.50.1"},"reference-count":0,"publisher":"Walter de Gruyter GmbH","issue":"11","content-domain":{"domain":[],"crossmark-restriction":false},"published-print":{"date-parts":[[1997,11,1]]},"abstract":"<jats:p>The isotypic borophosphates Rb[B<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub>(OH)] and Cs[B<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub>(OH)] were grown under hydrothermal conditions. The crystal structures were solved by single crystal methods (Rb[B<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub>(OH)]\/ Cs[B<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub>(OH)]: monoclinic, P2<jats:sub>1<\/jats:sub>\/c, a = 676.2(3)\/682.7(3), b = 1217.3(5)\/ 1236.8(5), c = 885.0(4)\/900.6(5) pm, \u03b2 = 97.3(1)\/ 98.1(1)\u00b0. Z = 4). The structures contain a complex framework of three-, four-, six-, nine- and twelvemembered rings of tetrahedra. Along [100] the twelve-membered rings are stacked to give wide channels which contain the Rb<jats:sup>+<\/jats:sup>\/Cs<jats:sup>+<\/jats:sup>-ions in an icosahedral coordination.<\/jats:p>","DOI":"10.1515\/znb-1997-1122","type":"journal-article","created":{"date-parts":[[2015,2,5]],"date-time":"2015-02-05T13:47:57Z","timestamp":1423144077000},"page":"1432-1435","source":"Crossref","is-referenced-by-count":34,"title":["Rb[B<sub>2<\/sub>P<sub>2<\/sub>O<sub>8<\/sub>(OH)] und Cs[B<sub>2<\/sub>P<sub>2<\/sub>O<sub>8<\/sub>(OH )]: Die ersten Borophosphate mit dreidimensional vernetzter Anionenteilstruktur  \/Rb[B<sub>2<\/sub>P<sub>2<\/sub>O<sub>8<\/sub>(OH)] and Cs[B<sub>2<\/sub>P<sub>2<\/sub>O<sub>8<\/sub>(OH )]: The First Borophosphates with a Threedimensional Anionic Tetrahedral Structure"],"prefix":"10.1515","volume":"52","author":[{"given":"Cornelia","family":"H\u00e4uf","sequence":"first","affiliation":[{"name":"Eduard-Zintl-Institut der Technischen Universit\u00e4t, Hochschulstr. 10, D-64289 Darmstadt"}]},{"given":"R\u00fcdiger","family":"Kniep","sequence":"additional","affiliation":[{"name":"Eduard-Zintl-Institut der Technischen Universit\u00e4t, Hochschulstr. 10, D-64289 Darmstadt"}]}],"member":"374","published-online":{"date-parts":[[2014,6,2]]},"container-title":["Zeitschrift f\u00fcr Naturforschung B"],"language":"en","link":[{"URL":"https:\/\/www.degruyter.com\/view\/journals\/znb\/52\/11\/article-p1432.xml","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1997-1122\/xml","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1997-1122\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,3,14]],"date-time":"2022-03-14T11:48:38Z","timestamp":1647258518000},"score":15.640214,"resource":{"primary":{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1997-1122\/html"}},"issued":{"date-parts":[[1997,11,1]]},"references-count":0,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2014,6,2]]},"published-print":{"date-parts":[[1997,11,1]]}},"alternative-id":["10.1515\/znb-1997-1122"],"URL":"https:\/\/doi.org\/10.1515\/znb-1997-1122","ISSN":["1865-7117","0932-0776"],"issn-type":[{"value":"1865-7117","type":"electronic"},{"value":"0932-0776","type":"print"}],"published":{"date-parts":[[1997,11,1]]}},{"indexed":{"date-parts":[[2026,1,30]],"date-time":"2026-01-30T06:45:32Z","timestamp":1769755532670,"version":"3.49.0"},"reference-count":10,"publisher":"Akademiai Kiado Zrt.","issue":"21","license":[{"start":{"date-parts":[[2023,5,28]],"date-time":"2023-05-28T00:00:00Z","timestamp":1685232000000},"content-version":"unspecified","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["akjournals.com"],"crossmark-restriction":true},"short-container-title":["OH"],"published-print":{"date-parts":[[2023,5,28]]},"abstract":"<jats:p>Az eg\u00e9szs\u00e9g\u00fcgyi \u00e9s az orvosbiol\u00f3giai kutat\u00e1sok adatainak sz\u00e9ttagolts\u00e1ga az\n                    adatvez\u00e9relt d\u00f6nt\u00e9seken alapul\u00f3, szem\u00e9lyre szabott orvosl\u00e1s egyik akad\u00e1lya. A\n                    fejl\u0151d\u00e9shez a m\u00e9retben \u00e9s komplexit\u00e1sban is rendk\u00edv\u00fcli, \u00e1m t\u00f6redezett\n                    eg\u00e9szs\u00e9g\u00fcgyi adatkincs hat\u00e9kony kiakn\u00e1z\u00e1s\u00e1t, illetve az int\u00e9zm\u00e9nyeken vagy ak\u00e1r\n                    hat\u00e1rokon is \u00e1t\u00edvel\u0151 adatmegoszt\u00e1st biztos\u00edt\u00f3 technol\u00f3gi\u00e1k sz\u00fcks\u00e9gesek. A\n                    biobankok nemcsak a mint\u00e1k arch\u00edvumai, hanem adatintegr\u00e1ci\u00f3s k\u00f6zpontok is\n                    egy\u00fattal. A biobankok adatainak egy\u00fcttm\u0171k\u00f6d\u00e9sben t\u00f6rt\u00e9n\u0151 elemz\u00e9se \u00e9rt\u00e9kesebb\n                    k\u00f6vetkeztet\u00e9seket \u00edg\u00e9r. Az adatok megoszt\u00e1s\u00e1nak el\u0151felt\u00e9tele a harmoniz\u00e1ci\u00f3,\n                    azaz a mint\u00e1k egyedi klinikai \u00e9s molekul\u00e1ris jellemz\u0151inek egys\u00e9ges adatmodellben\n                    \u00e9s standard k\u00f3dokkal t\u00f6rt\u00e9n\u0151 lek\u00e9pez\u00e9se. Az eg\u00e9szs\u00e9g\u00fcgyben keletkezett\n                    inform\u00e1ci\u00f3k ezekben a k\u00f6z\u00f6s s\u00e9m\u00e1ra illesztett adatb\u00e1zisokban v\u00e1lnak el\u00e9rhet\u0151v\u00e9 a\n                    g\u00e9pi tanul\u00e1s sz\u00e1m\u00e1ra, \u00edgy a m\u00f3dszer az egy\u00fcttm\u0171k\u00f6d\u00e9s sor\u00e1n a szem\u00e9lyes adatokat\n                    tiszteletben tart\u00f3 felhaszn\u00e1l\u00e1sra is lehet\u0151s\u00e9get ad. Az \u00e9rz\u00e9keny eg\u00e9szs\u00e9g\u00fcgyi\n                    adatok \u00fajra\u00e9rt\u00e9kel\u00e9se elk\u00e9pzelhetetlen a szem\u00e9lyes adatok v\u00e9delme n\u00e9lk\u00fcl,\n                    amelynek jogi \u00e9s koncepcion\u00e1lis kereteit a GDPR- (General Data Protection\n                    Regulation) \u00e9s a FAIR- (findable, accessible, interoperable, reusable) elvek\n                    jel\u00f6lik ki. Az Eur\u00f3p\u00e1ban m\u0171k\u00f6d\u0151 biobankok sz\u00e1m\u00e1ra a BBMRI-ERIC (Biobanking and\n                    Biomolecular Research Infrastructure \u2013 European Research Infrastructure\n                    Consortium) kutat\u00e1si infrastrukt\u00fara fejleszt k\u00f6z\u00f6s ir\u00e1nyelveket, amelyhez haz\u00e1nk\n                    2021-ben mint Magyar BBMRI Csom\u00f3pont csatlakozott. Els\u0151 l\u00e9p\u00e9sben a biobankok\n                    sz\u00f6vets\u00e9g\u00e9ben kapcsol\u00f3dhatnak \u00f6ssze a sz\u00e9ttagolt adathalmok, ahol sokr\u00e9t\u0171\n                    kutat\u00e1si c\u00e9l \u00e1ltal motiv\u00e1lt, ig\u00e9nyesen \u00f6sszerendezett adatk\u00e9szletek v\u00e1lnak\n                    hozz\u00e1f\u00e9rhet\u0151v\u00e9. Ezt k\u00f6vet\u0151en, a betegell\u00e1t\u00e1s val\u00f3s k\u00f6rnyezet\u00e9ben keletkezett\n                    adatok magasabb szinten t\u00f6rt\u00e9n\u0151 \u00e9rt\u00e9kel\u00e9se is lehet\u0151v\u00e9 v\u00e1lik, \u00edgy a klinikai\n                    vizsg\u00e1latok szigor\u00fa keretek k\u00f6z\u00f6tt gener\u00e1lt bizony\u00edt\u00e9kai \u00faj szintre ker\u00fclhetnek.\n                    K\u00f6zlem\u00e9ny\u00fcnkben a \u201efeder\u00e1lt\u201d adatmegoszt\u00e1sban rejl\u0151 lehet\u0151s\u00e9geket mutatjuk be a\n                    Semmelweis Egyetem biobankjainak k\u00f6z\u00f6s projektje kapcs\u00e1n. Orv Hetil. 2023;\n                    164(21): 811\u2013819.<\/jats:p>","DOI":"10.1556\/650.2023.32759","type":"journal-article","created":{"date-parts":[[2023,5,28]],"date-time":"2023-05-28T09:45:00Z","timestamp":1685267100000},"page":"811-819","update-policy":"https:\/\/doi.org\/10.1556\/policypage.crossmark.crossref.2","source":"Crossref","is-referenced-by-count":3,"title":["Az \u00e9rz\u00e9keny kutat\u00e1si adatok megoszt\u00e1sa a szem\u00e9lyre szabott orvosl\u00e1s gyakorlat\u00e1ban"],"prefix":"10.1556","volume":"164","author":[{"given":"Viktor","family":"Moln\u00e1r","sequence":"first","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, Genomikai Medicina \u00e9s Ritka Betegs\u00e9gek Int\u00e9zete Budapest, \u00dcll\u0151i \u00fat 26., 1085 Magyarorsz\u00e1g"}]},{"given":"Judit","family":"Cs. S\u00e1gi","sequence":"additional","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, Genomikai Medicina \u00e9s Ritka Betegs\u00e9gek Int\u00e9zete Budapest, \u00dcll\u0151i \u00fat 26., 1085 Magyarorsz\u00e1g"}]},{"given":"M\u00e1ria Judit","family":"Moln\u00e1r","sequence":"additional","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, Genomikai Medicina \u00e9s Ritka Betegs\u00e9gek Int\u00e9zete Budapest, \u00dcll\u0151i \u00fat 26., 1085 Magyarorsz\u00e1g"}]}],"member":"425","reference":[{"key":"ref0","doi-asserted-by":"publisher","unstructured":"Han, Y. Z.; Huang, H.; Zhang, H. C.; Liu, Y.; Han, X.; Liu, R. H.; Li, H. T.; Kang, Z. H. Carbon quantum dots with photoenhanced hydrogen-bond catalytic activity in aldol condensations. ACS Catal. 2014, 4, 781-787.","DOI":"10.1021\/cs401118x"},{"key":"ref1","doi-asserted-by":"publisher","unstructured":"Zhang, Y. H.; Zhang, N.; Tang, Z. R.; Xu, Y. J. Transforming CdS into an efficient visible light photocatalyst for selective oxidation of saturated primary C-H bonds under ambient conditions. Chem. Sci. 2012, 3, 2812-2822.","DOI":"10.1039\/c2sc20603j"},{"key":"ref2","doi-asserted-by":"publisher","unstructured":"Zhang, Z. Z.; Yang, Y. Y.; Wang, Y. Y.; Yang, L. L.; Li, Q.; Chen, L. X.; Xu, D. S. Revealing the A-site effect of lead-free A3Sb2Br9 perovskite in photocatalytic C(sp3)-H bond activation. Angew. Chem., Int. Ed. 2020, 59, 18136-18139.","DOI":"10.1002\/anie.202005495"},{"key":"ref3","doi-asserted-by":"publisher","unstructured":"Guo, X. N.; Hao, C. H.; Jin, G. Q.; Zhu, H. Y.; Guo, X. Y. Copper nanoparticles on graphene support: An efficient photocatalyst for coupling of nitroaromatics in visible light. Angew. Chem., Int. Ed. 2014, 53, 1973-1977.","DOI":"10.1002\/anie.201309482"},{"key":"ref4","doi-asserted-by":"publisher","unstructured":"Wang, H.; Wang, L.; Zhang, J.; Wang, C. T.; Liu, Z. Y.; Gao, X. H.; Meng, X. J.; Yoo, S. J.; Kim, J. G.; Zhang, W. et al. Interfacial CoOx layers on TiO2 as an efficient catalyst for solvent-free aerobic oxidation of hydrocarbons. ChemSusChem 2018, 11, 3965-3974.","DOI":"10.1002\/cssc.201801709"},{"key":"ref5","doi-asserted-by":"publisher","unstructured":"bin Saiman, M. I.; Brett, G. L.; Tiruvalam, R.; Forde, M. M.; Sharples, K.; Thetford, A.; Jenkins, R. L.; Dimitratos, N.; Lopez-Sanchez, J. A.; Murphy, D. M. et al. Involvement of surface-bound radicals in the oxidation of toluene using supported Au-Pd nanoparticles. Angew. Chem., Int. Ed. 2012, 51, 5981-5985.","DOI":"10.1002\/anie.201201059"},{"key":"ref6","doi-asserted-by":"publisher","unstructured":"Yuan, R. S.; Fan, S. L.; Zhou, H. X.; Ding, Z. X.; Lin, S.; Li, Z. H.; Zhang, Z. Z.; Xu, C.; Wu, L.; Wang, X. X. et al. Chlorine-radical-mediated photocatalytic activation of C-H bonds with visible light. Angew. Chem., Int. Ed. 2013, 52, 1035-1039.","DOI":"10.1002\/anie.201207904"},{"key":"ref7","doi-asserted-by":"publisher","unstructured":"Liu, Y.; Chen, L.; Yuan, Q.; He, J.; Au, C. T.; Yin, S. F. A green and efficient photocatalytic route for the highly-selective oxidation of saturated alpha-carbon C-H bonds in aromatic alkanes over flower-like Bi2WO6. Chem. Commun. 2016, 52, 1274-1277.","DOI":"10.1039\/C5CC07586F"},{"key":"ref8","doi-asserted-by":"publisher","unstructured":"Huang, H. W.; Yuan, H. F.; Zhao, J. W.; Sol\ufffds-Fern\ufffdndez, G.; Zhou, C.; Seo, J. W.; Hendrix, J.; Debroye, E.; Steele, J. A.; Hofkens, J. et al. C(sp3)-H bond activation by perovskite solar photocatalyst cell. ACS Energy Lett. 2019, 4, 203-208.","DOI":"10.1021\/acsenergylett.8b01698"},{"key":"ref9","doi-asserted-by":"publisher","unstructured":"Huang, Y.; Liu, C. B.; Li, M. Y.; Li, H. Z.; Li, Y. W.; Su, R.; Zhang, B. Photoimmobilized Ni clusters boost photodehydrogenative coupling of amines to imines via enhanced hydrogen evolution kinetics. ACS Catal. 2020, 10, 3904-3910.","DOI":"10.1021\/acscatal.0c00282"}],"container-title":["Orvosi Hetilap"],"link":[{"URL":"https:\/\/akjournals.com\/view\/journals\/650\/164\/21\/article-p811.xml","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/akjournals.com\/downloadpdf\/journals\/650\/164\/21\/article-p811.xml","content-type":"text\/html","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/akjournals.com\/downloadpdf\/journals\/650\/164\/21\/article-p811.xml","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T07:19:12Z","timestamp":1697699952000},"score":15.198717,"resource":{"primary":{"URL":"https:\/\/akjournals.com\/view\/journals\/650\/164\/21\/article-p811.xml"}},"issued":{"date-parts":[[2023,5,28]]},"references-count":10,"journal-issue":{"issue":"21"},"URL":"https:\/\/doi.org\/10.1556\/650.2023.32759","ISSN":["0030-6002","1788-6120"],"issn-type":[{"value":"0030-6002","type":"print"},{"value":"1788-6120","type":"electronic"}],"published":{"date-parts":[[2023,5,28]]}},{"indexed":{"date-parts":[[2026,3,14]],"date-time":"2026-03-14T06:00:39Z","timestamp":1773468039988,"version":"3.50.1"},"posted":{"date-parts":[[2026]]},"group-title":"SSRN","reference-count":49,"publisher":"Elsevier BV","content-domain":{"domain":[],"crossmark-restriction":false},"abstract":"<jats:p>To address the issues associated with conventional coal spontaneous combustion inhibition technologies, such as short-lived effectiveness, potential environmental pollution, and equipment corrosion, this study designed and fabricated a novel microcapsule composite material, PLA@CS\/nano-Mg(OH)2@APP, featuring a polylactic acid (PLA) shell and a composite core of chitosan (CS), nano-magnesium hydroxide (nano-Mg(OH)2), and ammonium polyphosphate (APP). The results indicated that the prepared composite material exhibited a regular, elongated cylindrical morphology with a complete and continuous coating layer, demonstrating good interfacial compatibility among its components. Among them, the PCMA-1:4 sample, with a PLA-to-composite-core mass ratio of 1:4, demonstrated the optimal performance in inhibiting coal spontaneous combustion. It reduced the cumulative oxygen consumption percentage of coal by 45.5%, increased the CO suppression rate to 43.9%, lowered the maximum mass loss rate by 37%, and raised the activation energy of the oxidation reaction by 77.2%. Furthermore, the flame retardant products formed a dense three-dimensional network char skeleton on the coal surface, with Mg and P flame-retardant elements uniformly distributed. The mechanism for inhibiting spontaneous combustion in the PLA@CS\/nano-Mg(OH)2@APP composite originates from the synergistic effects of several factors: the controlled release from the PLA shell, the endothermic decomposition of nano-Mg(OH)2, and the chemical chain scission achieved through free radical capture by APP and CS. These components work in concert to catalyze the formation of a dense carbon-MgO composite barrier layer on the coal surface. This study provides new insights and technical support for developing highly efficient, long-lasting, and environmentally friendly materials to inhibit coal spontaneous combustion.<\/jats:p>","DOI":"10.2139\/ssrn.6412723","type":"posted-content","created":{"date-parts":[[2026,3,14]],"date-time":"2026-03-14T05:08:32Z","timestamp":1773464912000},"source":"Crossref","is-referenced-by-count":0,"title":["Investigation of Microcapsule PLA@CS\/nano-Mg(OH)2@APP Composites: Inhibition of Coal Spontaneous Combustion and Analysis of Flame Retardant Products"],"prefix":"10.2139","author":[{"given":"Jinzhang","family":"Jia","sequence":"first","affiliation":[]},{"given":"Xiuyuan","family":"Tian","sequence":"additional","affiliation":[]},{"given":"Defu","family":"Che","sequence":"additional","affiliation":[]}],"member":"78","reference":[{"key":"ref1","first-page":"341","article-title":"Journey to burning half of global coal: Trajectory and drivers of China??? s coal use","volume":"58","author":"Q 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A feln\u0151tt\u00e9 v\u00e1l\u00e1s sor\u00e1n a kr\u00f3nikus gyermekkori betegs\u00e9gben\n                    szenved\u0151 egy\u00e9n a gyermekell\u00e1t\u00e1sb\u00f3l a feln\u0151ttell\u00e1t\u00e1sba val\u00f3 \u00e1tvezet\u00e9s\u00e9t (a\n                    tranz\u00edci\u00f3t) a betegs\u00e9gteher mellett tov\u00e1bbi neh\u00e9zs\u00e9gk\u00e9nt \u00e9lheti meg. A ritka\n                    betegs\u00e9gek eset\u00e9n ez az \u00e1tvezet\u00e9s m\u00e9g t\u00f6bb kih\u00edv\u00e1ssal j\u00e1rhat a gyakori kr\u00f3nikus\n                    betegs\u00e9gekben szenved\u0151k\u00e9vel \u00f6sszehasonl\u00edtva, mert a feln\u0151ttell\u00e1t\u00e1sban nem\n                    biztos, hogy minden eg\u00e9szs\u00e9g\u00fcgyi szolg\u00e1ltat\u00f3n\u00e1l megvan az a szakmai\n                    felk\u00e9sz\u00fclts\u00e9g, amely az optim\u00e1lis betegell\u00e1t\u00e1shoz sz\u00fcks\u00e9ges. Tov\u00e1bb\u00e1 az egyre\n                    hat\u00e1sosabb kezel\u00e9seknek k\u00f6sz\u00f6nhet\u0151en a kor\u00e1bbin\u00e1l hosszabb lesz a\n                    betegs\u00e9glefoly\u00e1s, \u00e9s \u00edgy olyan betegs\u00e9gekben jelentkezhet ig\u00e9ny a\n                    feln\u0151ttell\u00e1t\u00e1sra, amelyekben kor\u00e1bbr\u00f3l nincsen tapasztalat. Esetenk\u00e9nt olyan \u00faj\n                    klinikai t\u00fcnetegy\u00fcttesek jelenhetnek meg, melyek a klinikusok sz\u00e1m\u00e1ra m\u00e9g\n                    ismeretlenek. Az \u00e1tvezet\u00e9si folyamat a legt\u00f6bb ritka betegs\u00e9gben egyel\u0151re nem\n                    rendelkezik egys\u00e9ges ir\u00e1nyelvekkel, annak ellen\u00e9re sem, hogy ezek szerepe\n                    vitathatatlan. Irodalmi adatok alapj\u00e1n a j\u00f3 gyakorlat szerint a feln\u0151ttell\u00e1t\u00e1sba\n                    val\u00f3 \u00e1tt\u00e9r\u00e9snek minden esetben egy\u00e9nre szabottan, el\u0151zetesen kidolgozott terv\n                    szerint kell t\u00f6rt\u00e9nnie. Ide\u00e1lis esetben egy \u00e1tvezet\u00e9st seg\u00edt\u0151 koordin\u00e1tor\n                    t\u00e1mogatja a betegeket, aki tartja a kapcsolatot a gyermekgy\u00f3gy\u00e1sszal, a\n                    feln\u0151ttszakorvossal, a p\u00e1cienssel \u00e9s annak sz\u00fcleivel is. A beteg gyermek\n                    feln\u0151tt\u00e9 v\u00e1l\u00e1s\u00e1nak t\u00e1mogat\u00e1sa mellett a gondoz\u00f3k sz\u00fcks\u00e9gletei is fontos szerepet\n                    kapnak az \u00e1tvezet\u00e9s sor\u00e1n. Az optim\u00e1lis \u00e1tvezet\u00e9st els\u0151sorban a folyamatban\n                    r\u00e9szt vev\u0151k oktat\u00e1s\u00e1val, a folyamatot le\u00edr\u00f3 protokollok fejleszt\u00e9s\u00e9vel, valamint\n                    a megfelel\u0151 infrastrukt\u00fara biztos\u00edt\u00e1s\u00e1val lehet megval\u00f3s\u00edtani. Orv Hetil. 2022;\n                    163(51): 2021\u20132026.<\/jats:p>","DOI":"10.1556\/650.2022.32660","type":"journal-article","created":{"date-parts":[[2022,12,21]],"date-time":"2022-12-21T10:18:51Z","timestamp":1671617931000},"page":"2021-2026","update-policy":"http:\/\/dx.doi.org\/10.1556\/policypage.crossmark.crossref.1","source":"Crossref","is-referenced-by-count":5,"title":["A ritka betegs\u00e9gben szenved\u0151 gyermekek \u00e1tvezet\u00e9se a feln\u0151ttell\u00e1t\u00e1sba"],"prefix":"10.1556","volume":"163","author":[{"given":"M\u00e1ria Judit","family":"Moln\u00e1r","sequence":"first","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, Genomikai Medicina \u00e9s Ritka Betegs\u00e9gek Int\u00e9zete Budapest, \u00dcll\u0151i \u00fat 26., 1085 Magyarorsz\u00e1g"}]},{"given":"Judit","family":"Cs. S\u00e1gi","sequence":"additional","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, Genomikai Medicina \u00e9s Ritka Betegs\u00e9gek Int\u00e9zete Budapest, \u00dcll\u0151i \u00fat 26., 1085 Magyarorsz\u00e1g"}]},{"given":"L\u00e9na","family":"Szab\u00f3","sequence":"additional","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, II. Sz. Gyermekgy\u00f3gy\u00e1szati Klinika Budapest Magyarorsz\u00e1g"}]},{"given":"Zolt\u00e1n","family":"Grosz","sequence":"additional","affiliation":[{"name":"Semmelweis Egyetem, \u00c1ltal\u00e1nos Orvostudom\u00e1nyi Kar, Genomikai Medicina \u00e9s Ritka Betegs\u00e9gek Int\u00e9zete Budapest, \u00dcll\u0151i \u00fat 26., 1085 Magyarorsz\u00e1g"}]}],"member":"425","reference":[{"key":"ref0","unstructured":"1 Deden AC, Alma MA, Van Zelst-Stam WA. Understanding the diagnostic delay in rare diseases. 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