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Transitions are investigated by thermal analysis, mass spectra and <jats:sup>13<\/jats:sup>C NMR spectra. The vibrational spectra (I. R . and Raman) of the forms are discussed . The crystal structure of the monoclinic (Ph :GeO)<jats:sub>4<\/jats:sub> has been determined and refined to R = 0.051. The symmetry of the molecule is near to S<jats:sub>4<\/jats:sub> (distances Ge - O 174.7 - 176.2, Ge - C 190.0 - 194.6 pm, angles Ge - O - Ge 131.2 - 136.9, O - Ge - O 107.8 -110.3 \u00b0).<\/jats:p>","DOI":"10.1515\/znb-1984-0706","type":"journal-article","created":{"date-parts":[[2015,2,21]],"date-time":"2015-02-21T11:33:41Z","timestamp":1424518421000},"page":"868-875","source":"Crossref","is-referenced-by-count":20,"title":["Formen des Diphenylgermaniumoxids(Ph<sub>2<\/sub>GeO)<sub>x<\/sub>, x = 3, 4, n \/ Phases of Diphenylgermanium Oxide(Ph<sub>2<\/sub>GeO)<sub>x<\/sub>, x = 3, 4, n"],"prefix":"10.1515","volume":"39","author":[{"given":"Ludwig","family":"Ro\u00df","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie und Analytische Chemie der Johannes Gutenberg -Universit\u00e4t, Johann -Joachim -Becher-Weg 24, D -6500 Mainz"}]},{"given":"Martin","family":"Dr\u00e4ger","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie und Analytische Chemie der Johannes Gutenberg -Universit\u00e4t, Johann -Joachim -Becher-Weg 24, D -6500 Mainz"}]}],"member":"374","published-online":{"date-parts":[[2014,6,2]]},"container-title":["Zeitschrift f\u00fcr Naturforschung B"],"language":"en","link":[{"URL":"https:\/\/www.degruyter.com\/view\/journals\/znb\/39\/7\/article-p868.xml","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1984-0706\/xml","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1984-0706\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,6,23]],"date-time":"2021-06-23T12:16:43Z","timestamp":1624450603000},"score":17.383654,"resource":{"primary":{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znb-1984-0706\/html"}},"issued":{"date-parts":[[1984,7,1]]},"references-count":0,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2014,6,2]]},"published-print":{"date-parts":[[1984,7,1]]}},"alternative-id":["10.1515\/znb-1984-0706"],"URL":"https:\/\/doi.org\/10.1515\/znb-1984-0706","ISSN":["1865-7117","0932-0776"],"issn-type":[{"value":"1865-7117","type":"electronic"},{"value":"0932-0776","type":"print"}],"published":{"date-parts":[[1984,7,1]]}},{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T22:07:40Z","timestamp":1740175660836,"version":"3.37.3"},"reference-count":61,"publisher":"Springer Science and Business Media LLC","issue":"5","license":[{"start":{"date-parts":[[2022,10,1]],"date-time":"2022-10-01T00:00:00Z","timestamp":1664582400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T00:00:00Z","timestamp":1664928000000},"content-version":"vor","delay-in-days":4,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Geomech. 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The micro-physics model shows that a closed fracture cannot change to an open fracture by pressure changes alone; instead, bulk strain must elongate the porous rock in a direction normal to the fracture. Once opened, fracture apertures respond to changes in fluid pressure. A realistic context, within which the required bulk strain occurs, is the discontinuum geomechanics of fractured rock-mass systems, for which previous simulations exhibit a range of emergent local states that relate to the conditions, identified via the micro-physics, as being the essential controls on aperture evolution.<\/jats:p><\/jats:sec><jats:sec><jats:title>Article highlights<\/jats:title><jats:p><jats:list list-type=\"bullet\"><jats:list-item><jats:p>Discrete rock-texture model underpins micro-physics expressions that lead to macro-scale material response of matrix\/\/fracture<\/jats:p><\/jats:list-item><jats:list-item><jats:p>Closed fracture cannot open without local elongation normal to fracture; high pressure alone does not open fracture<\/jats:p><\/jats:list-item><jats:list-item><jats:p>Open fracture changes aperture with changing pressure<\/jats:p><\/jats:list-item><\/jats:list><\/jats:p><\/jats:sec>","DOI":"10.1007\/s40948-022-00484-1","type":"journal-article","created":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T14:55:10Z","timestamp":1664981710000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Discrete micro-physics interactions determine fracture apertures"],"prefix":"10.1007","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6039-6973","authenticated-orcid":false,"given":"Gary D.","family":"Couples","sequence":"first","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2022,10,5]]},"reference":[{"key":"484_CR1","doi-asserted-by":"publisher","first-page":"62","DOI":"10.1016\/j.ijrmms.2018.12.019","volume":"114","author":"S Ahmed","year":"2019","unstructured":"Ahmed S, M\u00fcller TM, Madadi M, Calo V (2019) Drained pore modulus and Biot coefficient from pore-scale digital rock simulations. 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Geophys. Geo-energ. Geo-resour."],"published-print":{"date-parts":[[2022,12]]},"abstract":"<jats:sec>\n                <jats:title>Abstract<\/jats:title>\n                <jats:p>Unconventional geo-resources are critical due to their important contributions to energy production. In this energy transition and sustainability era, there is an increased focus on CO<jats:sub>2<\/jats:sub>-enhanced oil recovery (CO<jats:sub>2<\/jats:sub>-EOR) and geological CO<jats:sub>2<\/jats:sub> storage (GCS) in unconventional hydrocarbon reservoirs, and the extraction of hot fluid for energy through enhanced geothermal systems. However, these energy solutions can only be achieved through efficient stimulation to develop a complex fracture network and pore structure in the host rocks to extract heat and hydrocarbon, or for CO<jats:sub>2<\/jats:sub> storage. Using Bakken formation well data and rock physics models, this study aimed to identify the post-depositional effect of pore structure on seismic velocity, elastic moduli, and formation fluid; and further predict the best lithofacies interval for well landing, and the implications for fluid (gas, oil, and water) recovery in naturally- and often systematically-fractured geosystems. The KT and DEM models' predictions show distinct formation intervals exhibiting needle-like pores and having higher seismic velocities (<jats:italic>V<\/jats:italic><jats:sub><jats:italic>p<\/jats:italic><\/jats:sub> and <jats:italic>V<\/jats:italic><jats:sub><jats:italic>s<\/jats:italic><\/jats:sub>) and elastic moduli (<jats:italic>K<\/jats:italic> and <jats:italic>\u00b5<\/jats:italic>), relative to other formation intervals that exhibit moldic pores. At the same fluid concentration, the needle-like pores (small aspect ratios) have a higher impact on elastic moduli, <jats:italic>V<\/jats:italic><jats:sub><jats:italic>p<\/jats:italic><\/jats:sub>, and <jats:italic>V<\/jats:italic><jats:sub><jats:italic>s<\/jats:italic><\/jats:sub> than on the moldic spherical pores with all other parameters held constant. <jats:italic>V<\/jats:italic><jats:sub><jats:italic>p<\/jats:italic><\/jats:sub> is affected more than <jats:italic>V<\/jats:italic><jats:sub><jats:italic>s<\/jats:italic><\/jats:sub> by the properties of the saturating fluid (gas, oil, or water) with <jats:italic>V<\/jats:italic><jats:sub><jats:italic>p<\/jats:italic><\/jats:sub> being greater in Bakken formation when it is water-saturated than when it is gas-saturated. <jats:italic>V<\/jats:italic><jats:sub><jats:italic>s<\/jats:italic><\/jats:sub> exhibit the reverse behavior, with <jats:italic>V<\/jats:italic><jats:sub><jats:italic>s<\/jats:italic><\/jats:sub> greater in the gas-saturated case than in the water-saturated case. Further, analyses suggest that the middle Bakken formation will have a higher susceptibility to fracturing and faulting, and hence will achieve greater fluid (oil and water) recovery. Our findings in this study provide insights that are relevant for fluid production and geo-storage in unconventional reservoirs.<\/jats:p>\n              <\/jats:sec><jats:sec>\n                <jats:title>Article highlights<\/jats:title>\n                <jats:p><jats:list list-type=\"bullet\">\n                  <jats:list-item>\n                    <jats:p>Integrated well log data and rock physics models.<\/jats:p>\n                  <\/jats:list-item>\n                  <jats:list-item>\n                    <jats:p>Investigated the effect of changes in pore structure on elastic properties and fluid flow in shale.<\/jats:p>\n                  <\/jats:list-item>\n                  <jats:list-item>\n                    <jats:p>Increase in porosity causes a reduction in elastic moduli and seismic velocities.<\/jats:p>\n                  <\/jats:list-item>\n                  <jats:list-item>\n                    <jats:p><jats:italic>V<\/jats:italic><jats:sub><jats:italic>p<\/jats:italic><\/jats:sub> is more affected by pore geometry than <jats:italic>V<\/jats:italic><jats:sub><jats:italic>s<\/jats:italic><\/jats:sub> depending on density and properties of saturating fluid.<\/jats:p>\n                  <\/jats:list-item>\n                  <jats:list-item>\n                    <jats:p>Lithofacies with needle\u2212like pores are more susceptible to fracturing than lithofacies with intragranular pores.<\/jats:p>\n                  <\/jats:list-item>\n                <\/jats:list><\/jats:p>\n              <\/jats:sec>","DOI":"10.1007\/s40948-022-00519-7","type":"journal-article","created":{"date-parts":[[2022,11,28]],"date-time":"2022-11-28T04:31:39Z","timestamp":1669609899000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Pore morphology effect on elastic and fluid flow properties in Bakken formation using rock physics modeling"],"prefix":"10.1007","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2726-2142","authenticated-orcid":false,"given":"Ogochukwu","family":"Ozotta","sequence":"first","affiliation":[]},{"given":"Mohammad Reza","family":"Saberi","sequence":"additional","affiliation":[]},{"given":"Oladoyin","family":"Kolawole","sequence":"additional","affiliation":[]},{"given":"Mohamed Lamine","family":"Malki","sequence":"additional","affiliation":[]},{"given":"Vamegh","family":"Rasouli","sequence":"additional","affiliation":[]},{"given":"Hui","family":"Pu","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2022,11,28]]},"reference":[{"key":"519_CR65","doi-asserted-by":"publisher","unstructured":"Anselmetti FS, Eberli GP (1999) The velocity deviation log: a tool to predict pore type permeability trends in carbonate drill holes from sonics and porosity or density logs. 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